Synthesis of a new bis(perfluoroalkyl oxirane) dioxyethylene ether
作者： Hayet Medini , Nejib Hussein Mekni , Ahmed Baklouti
DOI: 10.1016/J.JTUSCI.2014.10.001
关键词: Dioxirane 、 Ammonium chloride 、 Organic chemistry 、 Bromine 、 Phase-transfer catalyst 、 Mercuric acetate 、 Chemistry 、 Dioxyethylene Ether
摘要: Abstract Classic direct synthetic methods failed to transform bis(perfluororalkylallyl) dioxyethylene ether into the corresponding bis(perfluoroalkyl oxirane). This transformation was instead realized using a mixture of mercuric acetate/bromine produce bromoacetate, which subsequently transformed bromohydrin and further oxirane) through use triethylbenzyl ammonium chloride as phase transfer catalyst in alkaline media.
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