Suppression of dendritic lithium formation by using concentrated electrolyte solutions

作者: Soon-Ki Jeong , Hee-Young Seo , Dong-Hak Kim , Hyun-Kak Han , Jin-Gul Kim

DOI: 10.1016/J.ELECOM.2008.02.006

关键词: LithiumElectrochemistryDissolutionChemistryElectrolyteInorganic chemistryLithium batterySolvationPropylene carbonateConcentration effect

摘要: This study examined the electrochemical deposition and dissolution of lithium on nickel electrodes in a propylene carbonate (PC) electrolyte containing different LiN (SO2C2F5) 2 concentrations. The electrolyte concentration was found to have a significant effect on the reactions occurring at the electrode. The poor cycleability of the electrodes in the low-concentration solutions was improved considerably by increasing the electrolyte concentration. Transmission electron microscopy (TEM) revealed that a high-concentration …

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