Electric field dependent photocurrent generation in a thin-film organic photovoltaic device with a [70]fullerene–benzodifuranone dyad
作者： Pirmin A. Ulmann , Hideyuki Tanaka , Yutaka Matsuo , Zuo Xiao , Iwao Soga
DOI: 10.1039/C1CP22886B
关键词: Heterojunction 、 Moiety 、 Organic solar cell 、 Photocurrent 、 Chemistry 、 HOMO/LUMO 、 Acceptor 、 Fullerene 、 Thin film 、 Photochemistry
摘要: A [70]fullerene–benzodifuranone acceptor dyad synthesized by a Ag+-mediated coupling reaction was used to construct thin-film organic solar cell. The fullerene and the benzodifuranone dye in have close-lying LUMO levels range of 3.7–3.9 eV, so that energy transfer from can take place. p–n heterojunction photovoltaic device consisting tetrabenzoporphyrin showed weak but discernible contribution light absorption photocurrent under both positive negative effective bias. These results indicate moiety attached contributes light-harvesting transfer.
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M. A. Loi, Fulleropyrrolidine‐phthalocyanine: A New Molecule for Solar Energy Conversion Structural and Electronic Properties of Molecular Nanostructures. XVI International Winterschool on Electronic Properties of Novel Materials. ,vol. 633, pp. 488- 491 ,(2002) , 10.1063/1.1514168
Helmut Neugebauer, Maria Antonietta Loi, Christoph Winder, N Serdar Sariciftci, G Cerullo, Andreas Gouloumis, Purificación Vázquez, Tomás Torres, Photophysics and Photovoltaic Device Application of Fullerene Containing Phthalocyanine Dyads MOLECULAR NANOSTRUCTURES: XVII International Winterschool Euroconference on Electronic Properties of Novel Materials. ,vol. 685, pp. 537- 540 ,(2003) , 10.1063/1.1628088
Tero Kesti, Nikolai Tkachenko, Hiroko Yamada, Hiroshi Imahori, Shunichi Fukuzumi, Helge Lemmetyinen, C70vs. C60 in zinc porphyrin–fullerene dyads: prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin Photochemical and Photobiological Sciences. ,vol. 2, pp. 251- 258 ,(2003) , 10.1039/B210127K
M. Antonietta Loi, Patrick Denk, Harald Hoppe, Helmut Neugebauer, Christoph Winder, Dieter Meissner, Christoph Brabec, N. Serdar Sariciftci, Andreas Gouloumis, Purificación Vázquez, Tomás Torres, Long-lived photoinduced charge separation for solar cell applications in phthalocyanine–fulleropyrrolidine dyad thin films Journal of Materials Chemistry. ,vol. 13, pp. 700- 704 ,(2003) , 10.1039/B212621D
Kimmo Kaunisto, Vladimir Chukharev, Nikolai V. Tkachenko, Alexander Efimov, Helge Lemmetyinen, Energy and Electron Transfer in Multilayer Films Containing Porphyrin-Fullerene Dyad Journal of Physical Chemistry C. ,vol. 113, pp. 3819- 3825 ,(2009) , 10.1021/JP807962J
Yutaka Matsuo, Takahiko Ichiki, Shankara Gayathri Radhakrishnan, Dirk M. Guldi, Eiichi Nakamura, Loading Pentapod Deca(organo)[60]fullerenes with Electron Donors: From Photophysics to Photoelectrochemical Bilayers Journal of the American Chemical Society. ,vol. 132, pp. 6342- 6348 ,(2010) , 10.1021/JA909970H
Yumi Hizume, Kentaro Tashiro, Richard Charvet, Yohei Yamamoto, Akinori Saeki, Shu Seki, Takuzo Aida, Chiroselective assembly of a chiral porphyrin-fullerene dyad: photoconductive nanofiber with a top-class ambipolar charge-carrier mobility. Journal of the American Chemical Society. ,vol. 132, pp. 6628- 6629 ,(2010) , 10.1021/JA1014713
H. Tanaka, T. Yasuda, K. Fujita, T. Tsutsui, Transparent Image Sensors Using an Organic Multilayer Photodiode Advanced Materials. ,vol. 18, pp. 2230- 2233 ,(2006) , 10.1002/ADMA.200600163
H. Yamada, H. Imahori, Y. Nishimura, I. Yamazaki, S. Fukuzumi, Enhancement of Photocurrent Generation by ITO Electrodes Modified Chemically with Self‐Assembled Monolayers of Porphyrin–Fullerene Dyads Advanced Materials. ,vol. 14, pp. 892- 895 ,(2002) , 10.1002/1521-4095(20020618)14:12<892::AID-ADMA892>3.0.CO;2-U
C.W. Greenhalgh, J.L. Carey, D.F. Newton, The synthesis of quinodimethanes in the benzodifuranone and benzodipyrrolidone series Dyes and Pigments. ,vol. 1, pp. 103- 120 ,(1980) , 10.1016/0143-7208(80)80010-6