Relationships between the efficiency of cyclohexane oxidation and the electrochemical parameters of the reaction solution
作者： Alexander Pokutsa , Orest Fliunt , Yulia Kubaj , Tomasz Paczeŝniak , Pawel Blonarz
DOI: 10.1016/J.MOLCATA.2011.07.003
关键词: Oxalic acid 、 Process efficiency 、 Relative permittivity 、 Catalysis 、 Electrochemistry 、 Solvent 、 Chemistry 、 Inorganic chemistry 、 Cyclohexane 、 Yield (chemistry)
摘要: Abstract Vanadyl(IV)-acetylacetonate-catalyzed oxidation of cyclohexane with H2O2, at 40 °C under air atmosphere, has been studied in the presence small quantities oxalic acid. The process efficiency is increased by this additive and depends on nature solvent (MeCN ≥ MeOH > Me2CO ≥ 2-PrOH > EtOH). relationships between results (conversion, yield) electrochemical characteristics reaction solution (relative permittivity, redox-potential) are highlighted discussed.
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