Nanophase Materials: Synthesis, Structure, and Properties

作者: R. W. Siegel

DOI: 10.1007/978-3-642-46862-9_4

关键词: Grain boundaryCeramicNanotechnologyHigh resolution electron microscopyAtomChemistry

摘要: In the past few years, atom clusters with average diameters in range of 5–50 nm a variety materials, including metals and ceramics, have been synthesized by evaporation condensation high-purity gases followed consolidation situ under ultrahigh vacuum conditions to create nanophase materials. These new ultrafine-grained materials properties that are often significantly different considerably improved relative those their coarser-grained counterparts. The property changes result from small grain sizes, large percentage atoms boundary environments, interactions between grains. Since can be engineered during synthesis processing steps, cluster-assembled appear great technological potential beyond current scientific interest grain-size dependent properties. Recent research on is reviewed future considered.

参考文章(102)
G.J. Thomas, R.W. Siegel, J.A. Eastman, Grain boundaries in nanophase palladium: High resolution electron microscopy and image simulation☆ Scripta Metallurgica Et Materialia. ,vol. 24, pp. 201- 206 ,(1990) , 10.1016/0956-716X(90)90592-5
Hans Eckhardt Schaefer, R. Würschum, M. Scheytt, Rainer Birringer, H. Gleiter, The Structure of Nanocrystalline Metals Investigated by Positron Lifetime Spectroscopy Materials Science Forum. pp. 955- 962 ,(1987) , 10.4028/WWW.SCIENTIFIC.NET/MSF.15-18.955
K. Sattler, J. Mühlbach, E. Recknagel, Generation of Metal Clusters Containing from 2 to 500 Atoms Physical Review Letters. ,vol. 45, pp. 821- 824 ,(1980) , 10.1103/PHYSREVLETT.45.821
AH Heuer, DJ Fink, VJ Laraia, JL Arias, PD Calvert, K Kendall, GL Messing, J Blackwell, PC Rieke, DH Thompson, AP Wheeler, A Veis, AI Caplan, Innovative materials processing strategies: a biomimetic approach Science. ,vol. 255, pp. 1098- 1105 ,(1992) , 10.1126/SCIENCE.1546311
H. Chang, H.J. Höfler, C.J. Altstetter, R.S. Averback, Synthesis, processing and properties of nanophase TiAl Scripta Metallurgica Et Materialia. ,vol. 25, pp. 1161- 1166 ,(1991) , 10.1016/0956-716X(91)90521-2
Milton Blander, Monem Abdel-Gawad, The origin of meteorites and the constrained equilibrium condensation theory Geochimica et Cosmochimica Acta. ,vol. 33, pp. 701- 716 ,(1969) , 10.1016/0016-7037(69)90116-1
T. Mütschele, R. Kirchheim, Hydrogen as a probe for the average thickness of a grain boundary Scripta Metallurgica. ,vol. 21, pp. 1101- 1104 ,(1987) , 10.1016/0036-9748(87)90258-4
R.W. Siegel, G.J. Thomas, Grain boundaries in nanophase materials Ultramicroscopy. ,vol. 40, pp. 376- 384 ,(1992) , 10.1016/0304-3991(92)90135-7
Masahiro Uda, Production of ultrafine metal and alloy powders by hydrogen thermal plasma Nanostructured Materials. ,vol. 1, pp. 101- 106 ,(1992) , 10.1016/0965-9773(92)90060-B
J. C. Parker, R. W. Siegel, Raman microprobe study of nanophase TiO 2 and oxidation-induced spectral changes Journal of Materials Research. ,vol. 5, pp. 1246- 1252 ,(1990) , 10.1557/JMR.1990.1246