Synthesis and structural characterization of two copper(II) complexes constructed from copper(II) thenoyltrifluoroacetonate and the rigid imidazolyl-based ligands
作者： G. -F. Wang , S. -W. Sun , Q. -P. Han , W. -C. Zhang , H. Sun
DOI: 10.1134/S1063774514070219
关键词: Ion 、 Imidazole ligand 、 Atom 、 Crystallography 、 Chemistry 、 Base (chemistry) 、 Octahedron 、 Methanol 、 Stereochemistry 、 Copper 、 Nitrogen
摘要: Two copper(II) complexes, Cu(tta)2(L 1 )2 (1), 2 ) (2) (where L = 4-imidazolylbenzaldehyde, (E)-3-(4-(1H-imidazol-1-yl)phenyl)-1-(4-methoxyphenyl)prop-2-en-1-one) have been synthesized from the reaction of Cu(tta)2 with and in methanol medium, respectively. Their structures characterized by IR, elemental analyses single-crystal X-ray diffraction. The copper (II) ion is a distorted octahedral environment, which donor atoms are provided two oxygen tta ligands nitrogen ligands, while that square-pyramidal environment three O one N atom imidazole ligand lying at base.
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