Mechanism of improved magnetizing roasting of siderite–hematite iron ore using a synergistic CO–H 2 mixture

作者: Qiang Zhao , Ji-lai Xue , Wen Chen

DOI: 10.1007/S42243-019-00242-W

关键词: Iron oreScanning electron microscopeSideriteHematiteMaterials scienceRoastingMagnetiteIsothermal processSeparation processChemical engineering

摘要: A fluidized-bed magnetizing roasting–magnetic separation process was selected to treat this type of material. Phase transformations and microstructural changes in the product resulting from roasting under different reducing gases (CO, H2, CO + H2) were clarified by vibrating sample magnetometry, X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy. The results indicated that conversion ratio saturation magnetization samples roasted a mixed gas CO H2 higher than those produced or alone. This synergy combined had positive effect on process. mechanism kinetics improved siderite–hematite iron ore mixture synergistic CO–H2 system investigated isothermal conditions. apparent activation energies reactions oxides decreased 37.7 17.9 15.9 kJ/mol when atmosphere changed pure respectively. promoted hematite siderite magnetite, thereby improving

参考文章(29)
G. G. O. O. UWADIALE, Magnetizing Reduction of Iron Ores Mineral Processing and Extractive Metallurgy Review. ,vol. 11, pp. 1- 19 ,(1992) , 10.1080/08827509208914211
Siyi Luo, Cuijie Yi, Yangmin Zhou, Direct reduction of mixed biomass-Fe2O3 briquettes using biomass-generated syngas Renewable Energy. ,vol. 36, pp. 3332- 3336 ,(2011) , 10.1016/J.RENENE.2011.05.006
Shaojun Bai, Shuming Wen, Dianwen Liu, Wenbin Zhang, Yongjun Xian, Catalyzing Carbothermic Reduction of Siderite Ore with High Content of Phosphorus by Adding Sodium Carbonate Isij International. ,vol. 51, pp. 1601- 1607 ,(2011) , 10.2355/ISIJINTERNATIONAL.51.1601
Tiejun Chun, Deqing Zhu, Jian Pan, Simultaneously Roasting and Magnetic Separation to Treat Low Grade Siderite and Hematite Ores Mineral Processing and Extractive Metallurgy Review. ,vol. 36, pp. 223- 226 ,(2015) , 10.1080/08827508.2014.928620
S. N. Rychagov, A. A. Nuzhdaev, I. I. Stepanovb, Mercury as an indicator of modern ore-forming gas—hydrothermal systems, Kamchatka Geochemistry International. ,vol. 52, pp. 131- 143 ,(2014) , 10.1134/S0016702913120082
Hideki Ono-Nakazato, Toshinari Yonezawa, Tateo Usui, Effect of Water-Gas Shift Reaction on Reduction of Iron Oxide Powder Packed Bed with H2-CO Mixtures ISIJ International. ,vol. 43, pp. 1502- 1511 ,(2003) , 10.2355/ISIJINTERNATIONAL.43.1502
S Song, S Lu, A Lopez-Valdivieso, Magnetic separation of hematite and limonite fines as hydrophobic flocs from iron ores Minerals Engineering. ,vol. 15, pp. 415- 422 ,(2002) , 10.1016/S0892-6875(02)00054-7
V. I. Matyukhin, S. G. Melamud, V. V. Shatsillo, O. V. Matyukhin, A. V. Matyukhina, Исследование особенностей обжига мелких фракций сидерита во вращающейся печи Современные научные достижения металлургической теплотехники и их реализация в промышленности. — Екатеринбург, 2015.. ,vol. 58, pp. 652- 657 ,(2015) , 10.17073/0368-0797-2015-9-652-657
Zijian Su, Yuanbo Zhang, Jun Chen, Bingbing Liu, Guanghui Li, Tao Jiang, Selective separation and recovery of iron and tin from high calcium type tin- and iron-bearing tailings using magnetizing roasting followed by magnetic separation Separation Science and Technology. ,vol. 51, pp. 1900- 1912 ,(2016) , 10.1080/01496395.2016.1178292