A new strategy for polybenzoxazine-montmorillonite nanocomposites synthesis
作者： S.A. Gârea , H. Iovu , A. Nicolescu , C. Deleanu
DOI: 10.1016/J.POLYMERTESTING.2009.01.009
关键词: Nanocomposite 、 Thermosetting polymer 、 Montmorillonite 、 Materials science 、 End-group 、 Monomer 、 Polymer chemistry 、 Bisphenol A 、 Fourier transform infrared spectroscopy 、 Gel permeation chromatography
摘要: Abstract New polyether substituted benzoxazine monomers were synthesized starting from bisphenol A and p-Cresole as phenolic component various polyetheramines. The chemical structures proved by FTIR, 1H-NMR, 13C-NMR, 15N-NMR gel permeation chromatography (GPC). new benzoxazines mixed with classical based on benzylamine (BA-BZA) reinforced modified montmorillonite to give nanocomposites which characterized transmission electron microscopy (TEM). structure of the nanocomposite is exfoliated only when a high compatibility ensured between comonomers montmorillonite, this being case for same chain that modifier agent montmorillonite.
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sci-hub.se 参考文章(15)
Tsutomu Takeichi, Yong Guo, Tarek Agag, Synthesis and characterization of poly(urethane‐benzoxazine) films as novel type of polyurethane/phenolic resin composites Journal of Polymer Science Part A. ,vol. 38, pp. 4165- 4176 ,(2000) , 10.1002/1099-0518(20001115)38:22<4165::AID-POLA170>3.0.CO;2-S
Phairat Phiriyawirut, Rathanawan Magaraphan, Hatsuo Ishida, Preparation and characterization of polybenzoxazine-clay immiscible nanocomposite Materials Research Innovations. ,vol. 4, pp. 187- 196 ,(2001) , 10.1007/S100190000079
Tarek Agag, Hajime Tsuchiya, Tsutomu Takeichi, Novel organic–inorganic hybrids prepared from polybenzoxazine and titania using sol–gel process Polymer. ,vol. 45, pp. 7903- 7910 ,(2004) , 10.1016/J.POLYMER.2004.09.022
Tsutomu Takeichi, Takuya Kano, Tarek Agag, Synthesis and thermal cure of high molecular weight polybenzoxazine precursors and the properties of the thermosets Polymer. ,vol. 46, pp. 12172- 12180 ,(2005) , 10.1016/J.POLYMER.2005.10.088
Sorina-Alexandra Gârea, Horia Iovu, Alina Nicolescu, Calin Deleanu, Thermal polymerization of benzoxazine monomers followed by GPC, FTIR and DETA Polymer Testing. ,vol. 26, pp. 162- 171 ,(2007) , 10.1016/J.POLYMERTESTING.2006.09.011
Qiao Chen, Riwei Xu, Dingsheng Yu, Multiwalled carbon nanotube/polybenzoxazine nanocomposites: Preparation, characterization and properties Polymer. ,vol. 47, pp. 7711- 7719 ,(2006) , 10.1016/J.POLYMER.2006.08.058
Tsutomu Takeichi, Rachib Zeidam, Tarek Agag, Polybenzoxazine/clay hybrid nanocomposites: influence of preparation method on the curing behavior and properties of polybenzoxazines Polymer. ,vol. 43, pp. 45- 53 ,(2002) , 10.1016/S0032-3861(01)00604-8
Tsutomu Takeichi, Tarek Agag, High Performance Polybenzoxazines as Novel Thermosets High Performance Polymers. ,vol. 18, pp. 777- 797 ,(2006) , 10.1177/0954008306068254
Sorina-Alexandra Gârea, Horia Iovu, New epoxy coating systems which contain multipurpose additives based on organophilic montmorillonite Progress in Organic Coatings. ,vol. 56, pp. 319- 326 ,(2006) , 10.1016/J.PORGCOAT.2006.06.004
Yuan-Jyh Lee, Shiao-Wei Kuo, Chih-Feng Huang, Feng-Chih Chang, Synthesis and characterization of polybenzoxazine networks nanocomposites containing multifunctional polyhedral oligomeric silsesquioxane (POSS) Polymer. ,vol. 47, pp. 4378- 4386 ,(2006) , 10.1016/J.POLYMER.2006.03.111