Four-Coordinate Mo(II) as (silox)2Mo(PMe3)2and Its W(IV) Congener (silox)2HW(η2-CH2PMe2)(PMe3) (silox = tBu3SiO)

作者: David S. Kuiper , Peter T. Wolczanski , Emil B. Lobkovsky , Thomas R. Cundari

DOI: 10.1021/IC8011958

关键词: CongenerOrganic chemistryChemistryMedicinal chemistryMolybdenum

摘要: The reduction of [(t Bu3SiO) 2MoCl] 2 (2 2) provided the cyclometalated derivative,(silox) 2HMoMo (κ-O, C-OSi t Bu2CMe2CH2)(silox)(3), and alkylation of 2 2 with MeMgBr afforded …

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