作者： Roy A. Periana , Gaurav Bhalla , Xiang Yang Liu , C. J. Jones , Antek Wong-Foy
DOI:
关键词: Chemistry 、 C h bond 、 Catalysis 、 Medicinal chemistry 、 Alkane 、 Metal 、 Elimination reaction 、 Stereochemistry
摘要: Summary In summary, we demonstrated that well-defined, late metal, O-ligated complexes are competent for alkane C-H activation, exhibit high thermal and protic stability efficient catalysts H/D exchange reactions with alkanes. 13 C-labeling studies show these O-donor Ir-alkyl may likely undergo reversible β-hydride elimination unproductive respect to stable olefinic products. It will be interesting further explore understand the differences between new metal known Cp, P or N-donor systems CH activation reaction. Given unusual of systems, currently investigating oxidative functionalization M-R activate bonds. Acknowledgement We thank National Science Foundation (CHE-03 28 1) Chevron Texaco Energy Research Technology Company financial support this research.