A New Intermediate in Copper Dioxygen Chemistry: Breaking the O-O Bond To Form a {Cu2(.mu.-O)2}2+ Core

作者: Samiran Mahapatra , Jason A. Halfen , Elizabeth C. Wilkinson , Gaofeng Pan , Christopher J. Cramer

DOI: 10.1021/JA00139A026

关键词: ChemistryReaction intermediateCatalysisMoleculePhotochemistryCopperChemical bondCrystallographyDissociation (chemistry)RedoxRaman spectroscopy

摘要: … is comprised of strong bonding interactions between the two … 0—0 bond in the (u-Oh species (see supporting information). … we propose may form immediately subsequent todioxygen …

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