Solid state synthesis, thermodynamics and catalytic combustion effect of a high energy nickel(II) coordination compound
作者： Qi Yang , Qing Wei , San-Ping Chen , Guo-Chun Zhang , Chun-Sheng Zhou
DOI: 10.1016/J.JAAP.2012.10.026
关键词: Inorganic chemistry 、 Enthalpy 、 Coordination complex 、 Catalytic combustion 、 Nickel 、 Molecule 、 Chemistry 、 Physical chemistry 、 Thermal decomposition 、 Ammonium perchlorate 、 Isothermal microcalorimetry
摘要: Abstract Self-assembly of Ni(II) with 3,5-diamino-1,2,4-triazole resulted in a 3D supramolecular compound [Ni3(Hdatrz)6(fma)2(H2O)4]fma·11H2O (1) the presence coligand fumaric acid (Hdatrz = 3,5-diamino-1,2,4-triazole, H2fma = fumaric acid). X-ray structural analysis reveals that three nickel ions are bridged by six neutral Hdatrz ligands, and abundant lattice water molecules exist 1. Based on framework TG curve 1, new energetic [Ni3(Hdatrz)6(fma)2(H2O)4]fma (2) 35.5% nitrogen content was readily prepared through dehydration 1 at 398 K under N2 atmosphere. The enthalpy change reaction formation for determined to be (−23.24 ± 0.05) kJ mol−1 microcalorimetry (298.15 ± 0.01) K. Thermodynamic thermokinetic parameters k, E, n, Δ S ≠ θ , H G were obtained. Thermoanalytical kinetics 2 further investigated. sensitivity experiment results indicated more sensitive impact friction stimuli As an additive, effectively promoted thermal decomposition ammonium perchlorate (AP), which projected potential application as combustion modifier solid propellants.
sci-hub.se 参考文章(29)
L.-J. Chen, G.-S. Li, L.-P. Li, CuO nanocrystals in thermal decomposition of ammonium perchlorate Journal of Thermal Analysis and Calorimetry. ,vol. 91, pp. 581- 587 ,(2008) , 10.1007/S10973-007-8496-7
G. Shengli, J. Mian, C. Sanping, H. Rongzu, S. Qizhen, The thermokinetics of the formation reaction of cobalt histidine complex Journal of Thermal Analysis and Calorimetry. ,vol. 66, pp. 423- 429 ,(2001) , 10.1023/A:1013134616223
H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Analytical Chemistry. ,vol. 29, pp. 1702- 1706 ,(1957) , 10.1021/AC60131A045
Gurdip Singh, S Prem Felix, Studies on energetic compounds 25. An overview of preparation, thermolysis and applications of the salts of 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) Journal of Hazardous Materials. ,vol. 90, pp. 1- 17 ,(2002) , 10.1016/S0304-3894(01)00349-1
Hongbo Liu, Qingze Jiao, Yun Zhao, Hansheng Li, Chongbo Sun, Xuefei Li, HongyuWu, Cu/Fe hydrotalcite derived mixed oxides as new catalyst for thermal decomposition of ammonium perchlorate Materials Letters. ,vol. 64, pp. 1698- 1700 ,(2010) , 10.1016/J.MATLET.2010.04.061
Yan Cui, Jianguo Zhang, Tonglai Zhang, Li Yang, Jin Zhang, Xiaochun Hu, Synthesis, structural investigation, thermal decomposition mechanism and sensitivity properties of an energetic compound [Cd(DAT)6](ClO4)2 (DAT=1,5-diaminotetrazole) Journal of Hazardous Materials. ,vol. 160, pp. 45- 50 ,(2008) , 10.1016/J.JHAZMAT.2008.02.078
Stanisław Cudziło, Marcin Nita, Synthesis and explosive properties of copper(II) chlorate(VII) coordination polymer with 4-amino-1,2,4-triazole bridging ligand Journal of Hazardous Materials. ,vol. 177, pp. 146- 149 ,(2010) , 10.1016/J.JHAZMAT.2009.12.008
Thomas M. Klapötke, Carles Miró Sabaté, Alexander Penger, Magdalena Rusan, Jan M. Welch, Energetic Salts of Low-Symmetry Methylated 5-Aminotetrazoles European Journal of Inorganic Chemistry. ,vol. 2009, pp. 880- 896 ,(2009) , 10.1002/EJIC.200800995
Xuefei Sun, Xiaoqing Qiu, Liping Li, Guangshe Li, ZnO twin-cones: synthesis, photoluminescence, and catalytic decomposition of ammonium perchlorate. Inorganic Chemistry. ,vol. 47, pp. 4146- 4152 ,(2008) , 10.1021/IC702348C
Thomas M. Klapötke, Carles Miró Sabaté, Bistetrazoles: Nitrogen-Rich, High-Performing, Insensitive Energetic Compounds Chemistry of Materials. ,vol. 20, pp. 3629- 3637 ,(2008) , 10.1021/CM703657K