Reactions of ionic species from acetonitrile with long-chain saturated and unsaturated alcohols
作者： Gloriano Moneti , Giuseppe Pieraccini , Donata Favretto , Pietro Traldi
DOI: 10.1002/(SICI)1096-9888(199912)34:12<1354::AID-JMS894>3.0.CO;2-1
关键词: Reaction mechanism 、 Analytical chemistry 、 Ionic bonding 、 Chemical ionization 、 Double bond 、 Mass spectrum 、 Chemistry 、 Medicinal chemistry 、 Nitrile 、 Acetonitrile 、 Alcohol
摘要: Ten long-chain saturated and unsaturated alcohols were reacted with the ionic species [C(2) H(2) N](+) [C(3) H(4) generated by ionization of acetonitrile into an ion trap. The mass spectra compounds under investigation show formation [M -H](+), + C(2) ions in case alcohols, whereas for monounsaturated polyunsaturated derivatives additional peaks corresponding to H](+) H -H(2) O](+) are observed. reaction mechanisms investigated means D- (13)C-labelled acetonitrile. Collisional experiments performed on C(3) from order identify any possibly diagnostic fragments identification double bond positions. Copyright 1999 John Wiley & Sons, Ltd.
harvard.edu
sci-hub.se 参考文章(15)
H. Wincel, R.H. Fokkens, N.M.M. Nibbering, On the rearrangement of the cyanomethyl cation derived from gaseous acetonitrile International Journal of Mass Spectrometry and Ion Processes. ,vol. 96, pp. 321- 330 ,(1990) , 10.1016/0168-1176(90)85132-L
H. Schlager, F. Arnold, Balloon-borne fragment ion mass spectrometry studies of stratospheric positive ions: Unambiguous detection of H+(CH3CN)1(H2O)m-clusters Planetary and Space Science. ,vol. 33, pp. 1363- 1366 ,(1985) , 10.1016/0032-0633(85)90015-7
B.E. Turner, Recent progress in astrochemistry Space Science Reviews. ,vol. 51, pp. 235- 337 ,(1989) , 10.1007/BF00172023
G. Brasseur, R. Zellner, A. De Rudder, E. Arijs, Is hydrogen cyanide (HCN) a progenitor of acetonitrile (CH3CN) in the atmosphere Geophysical Research Letters. ,vol. 12, pp. 117- 120 ,(1985) , 10.1029/GL012I003P00117
Gloriano Moneti, Giuseppe Pieraccini, Donata Favretto, Pietro Traldi, Acetonitrile in chemical ionization of monounsaturated hydrocarbons: a13C and2H labeling study Journal of Mass Spectrometry. ,vol. 33, pp. 1148- 1149 ,(1998) , 10.1002/(SICI)1096-9888(1998110)33:11<1148::AID-JMS707>3.0.CO;2-Y
H. Böhringer, F. Arnold, Acetonitrile in the stratosphere—implications from laboratory studies Nature. ,vol. 290, pp. 321- 322 ,(1981) , 10.1038/290321A0
H. Wincel, Gas-phase equilibria studies of C2H2N+ and C3H4N+ with CH3CN International Journal of Mass Spectrometry and Ion Processes. ,vol. 175, pp. 283- 291 ,(1998) , 10.1016/S0168-1176(98)00100-1
O. Bortolini, L. Pandolfo, C. Tomaselli, P. Traldi, Ion-molecule chemistry of carbon suboxide in an ion-trap mass spectrometer International Journal of Mass Spectrometry. ,vol. 190, pp. 171- 179 ,(1999) , 10.1016/S1387-3806(98)14292-6
GLORIANO MONETI, GIUSEPPE PIERACCINI, FRANCESCA DANI, STEFANO TURILLAZZI, DONATA FAVRETTO, PIETRO TRALDI, Ion–molecule reactions of ionic species from acetonitrile with unsaturated hydrocarbons for the identification of the double‐bond position using an ion trap Journal of Mass Spectrometry. ,vol. 32, pp. 1371- 1373 ,(1997) , 10.1002/(SICI)1096-9888(199712)32:12<1371::AID-JMS588>3.0.CO;2-E
Gloriano Moneti, Giuseppe Pieraccini, Francesca R. Dani, Silvia Catinella, Pietro Traldi, ACETONITRILE AS AN EFFECTIVE REACTANT SPECIES FOR POSITIVE-ION CHEMICAL IONIZATION OF HYDROCARBONS BY ION-TRAP MASS SPECTROMETRY Rapid Communications in Mass Spectrometry. ,vol. 10, pp. 167- 170 ,(1996) , 10.1002/(SICI)1097-0231(19960131)10:2<167::AID-RCM445>3.0.CO;2-Q