Synthesis of titanium polythioethers

作者: Charles E. Carraher , Robert J. Nordin

DOI: 10.1002/POL.1972.150100217

关键词: TitaniumAqueous solutionCyclopentadienyl complexInorganic chemistryConstant (mathematics)ChemistryYield (chemistry)

摘要: The synthesis of polythioethers the form was effected, where Cp denotes cyclopentadienyl. Four reaction systems were studied and evaluated. Two proved to be undesirable (the “reverse” interfacial organic solution methods), while two acceptable “normal” aqueous methods). A number added bases Et3N NaOH found acceptable. Yield increases with time for syntheses, yield remains constant via normal method.

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