Measurements of (∂V∂T)p, (∂V∂P)T, and (∂H∂T)p by flux calorimetry

作者: Jean Claude Petit , Léon Ter Minassian

DOI: 10.1016/0021-9614(74)90150-5

关键词: ChemistryThermodynamicsHeat capacityHexadecaneCyclohexanolFundamental thermodynamic relationAnalytical chemistryCalorimetryFluxCompressibility

摘要: Abstract Flux calorimetry is employed to obtain ( ∂V ∂T ) p and ∂p T by use of Maxwell's thermodynamic relations. The method thus provides a measurement thermal expansivity isothermal compressibility, also heat capacity, using single liquid sample. Results for hexadecane, butane-1,4-diol, 1,2,4-trimethylbenzene, cyclohexanol are compared with previous values.

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