Spectrofluorometric study of thallium (I) complexes with several macrocyclic ligands in methanol solution.
作者： Hooshang Parham , Mojtaba Shamsipur
DOI: 10.1016/0039-9140(93)80209-A
关键词: Medicinal chemistry 、 Methanol 、 Ring (chemistry) 、 Chemistry 、 Dicyclohexyl-18-crown-6 、 Fluorescence 、 Thallium 、 Inorganic chemistry 、 Selectivity
摘要: Abstract The fluorescent signal of T1 + was employed as a sensitive probe to study the complexation reactions between this cation and several macrocyclic ligands in methanol solution at 20°C. stability constants resulting 1:1 complexes were determined found vary order C222 > C221 18C6 DC18C6 DB30C10 DB18C6 15C5 DA18C6 B15C5 DA15C5. influence number members macrocycle nature substituents on polyether ring dimensionality selectivity is discussed.
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sci-hub.se 参考文章(15)
Abolfazl Semnani, Mojtaba Shamsipur, A competitive polarographic study of alkaline earth complexes with some crown ethers using the Tl(I)/Tl(Hg) couple as an electrochemical probe Journal of Electroanalytical Chemistry. ,vol. 315, pp. 95- 101 ,(1991) , 10.1016/0022-0728(91)80062-U
James L. Dye, Vincent A. Nicely, A general purpose curve fitting program for class and research use Journal of Chemical Education. ,vol. 48, pp. 443- ,(1971) , 10.1021/ED048P443
Soheila Kashanian, Mojtaba Shamsipur, Complex formation of alkaline earth cations with benzo-15-crown-5 and some 18-crowns in methanol, dimethylformamide and dimethyl sulfoxide solutions Inorganica Chimica Acta. ,vol. 155, pp. 203- 206 ,(1989) , 10.1016/S0020-1693(00)90410-9
Hans K. Frensdorff, Stability constants of cyclic polyether complexes with univalent cations Journal of the American Chemical Society. ,vol. 93, pp. 600- 606 ,(1971) , 10.1021/JA00732A007
F.J. Kayne, Thallium (I) activation of pyruvate kinase. Archives of Biochemistry and Biophysics. ,vol. 143, pp. 232- 239 ,(1971) , 10.1016/0003-9861(71)90204-9
Mojtaba. Shamsipur, Alexander I. Popov, Cesium-133 NMR study of the kinetics of cesium ion complexation by 1,10-diaza-18-crown-6 and cryptand C221 in some nonaqueous solutions The Journal of Physical Chemistry. ,vol. 91, pp. 447- 451 ,(1987) , 10.1021/J100286A038
Hooshang Parham, Mojtaba Shamsipur, Polarographic study of the interaction between heavy metal ions and some macrocyclic ligands in binary Acctonitrile + water mixtures Journal of Electroanalytical Chemistry. ,vol. 314, pp. 71- 80 ,(1991) , 10.1016/0022-0728(91)85429-S
Frederick J. Kayne, Jacques. Reuben, Thallium-205 nuclear magnetic resonance as a probe for studying metal ion binding to biological macromolecules. Estimate of the distance between the monovalent and divalent activators of pyruvate kinase Journal of the American Chemical Society. ,vol. 92, pp. 220- 222 ,(1970) , 10.1021/JA00704A048
John S. Britten, Martin Blank, Thallium activation of the (Na+--K+)-activated ATPase of rabbit kidney. Biochimica et Biophysica Acta. ,vol. 159, pp. 160- 166 ,(1968) , 10.1016/0005-2744(68)90254-4
Hooshang Parham, Mojtaba Shamsipur, Spectrophotometric study of some alkali and alkaline earth cryptates in dimethylformamide solution using murexide as a metallochromic indicator Polyhedron. ,vol. 11, pp. 987- 991 ,(1992) , 10.1016/S0277-5387(00)83352-5