Temperature-controlled phase-transfer catalysis for ethylene glycol production from cellulose.
作者： Zhijun Tai , Junying Zhang , Aiqin Wang , Mingyuan Zheng , Tao Zhang
DOI: 10.1039/C2CC32305B
关键词: Phase (matter) 、 Cellobiose 、 Heterogeneous catalysis 、 Organic chemistry 、 Catalysis 、 Cellulose 、 Yield (chemistry) 、 Chemistry 、 Binary system 、 Ethylene glycol
摘要: A temperature-controlled phase-transfer catalyst-tungsten acid, which in combination with a robust heterogeneous catalyst Ru/C shows high activity and exceptional reusability for the one-pot conversion of cellulose to ethylene glycol. This binary system can be reused more than 20 times glycol yield over 50%.
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irgrid.ac.cn参考文章(23)
X. Zuwei, Reaction-controlled phase-transfer catalysis for propylene epoxidation to propylene oxide Science. ,vol. 292, pp. 1139- 1141 ,(2001) , 10.1126/SCIENCE.292.5519.1139
Mitsuru Sasaki, Kohtaro Goto, Kiyohiko Tajima, Tadafumi Adschiri, Kunio Arai, Rapid and selective retro-aldol condensation of glucose to glycolaldehyde in supercritical water Green Chemistry. ,vol. 4, pp. 285- 287 ,(2002) , 10.1039/B203968K
Jan Geboers, Stijn Van de Vyver, Kevin Carpentier, Pierre Jacobs, Bert Sels, Efficient hydrolytic hydrogenation of cellulose in the presence of Ru-loaded zeolites and trace amounts of mineral acid Chemical Communications. ,vol. 47, pp. 5590- 5592 ,(2011) , 10.1039/C1CC10422E
Mi Liu, Weiping Deng, Qinghong Zhang, Yanliang Wang, Ye Wang, Polyoxometalate-supported ruthenium nanoparticles as bifunctional heterogeneous catalysts for the conversions of cellobiose and cellulose into sorbitol under mild conditions Chemical Communications. ,vol. 47, pp. 9717- 9719 ,(2011) , 10.1039/C1CC12506K
Na Ji, Tao Zhang, Mingyuan Zheng, Aiqin Wang, Hui Wang, Xiaodong Wang, Jingguang G. Chen, Direct catalytic conversion of cellulose into ethylene glycol using nickel-promoted tungsten carbide catalysts. Angewandte Chemie. ,vol. 47, pp. 8510- 8513 ,(2008) , 10.1002/ANIE.200803233
L. Bartha, A.B. Kiss, T. Szalay, Chemistry of tungsten oxide bronzes International Journal of Refractory Metals & Hard Materials. ,vol. 13, pp. 77- 91 ,(1995) , 10.1016/0263-4368(94)00031-X
Li-Ning Ding, Ai-Qin Wang, Ming-Yuan Zheng, Tao Zhang, Selective Transformation of Cellulose into Sorbitol by Using a Bifunctional Nickel Phosphide Catalyst Chemsuschem. ,vol. 3, pp. 818- 821 ,(2010) , 10.1002/CSSC.201000092
Jifeng Pang, Aiqin Wang, Mingyuan Zheng, Yanhua Zhang, Yanqiang Huang, Xiaowei Chen, Tao Zhang, Catalytic conversion of cellulose to hexitols with mesoporous carbon supported Ni-based bimetallic catalysts Green Chemistry. ,vol. 14, pp. 614- 617 ,(2012) , 10.1039/C2GC16364K
Likun Zhou, Aiqin Wang, Changzhi Li, Mingyuan Zheng, Tao Zhang, Selective Production of 1,2‐Propylene Glycol from Jerusalem Artichoke Tuber using Ni–W2C/AC Catalysts Chemsuschem. ,vol. 5, pp. 932- 938 ,(2012) , 10.1002/CSSC.201100545
Mitsuru Sasaki, Momoko Furukawa, Kimitaka Minami, Tadafumi Adschiri, Kunio Arai, Kinetics and mechanism of cellobiose hydrolysis and retro-aldol condensation in subcritical and supercritical water Industrial & Engineering Chemistry Research. ,vol. 41, pp. 6642- 6649 ,(2002) , 10.1021/IE020326B