Inhibition of the electrode reaction in the presence of surfactants studied by differential pulse polarography: Cadmium(II) in seawater in the presence of the Triton-X-100☆
作者： Z. Kozarac , S. Nikolić , I. Ružić , B. Ćosović
DOI: 10.1016/0022-0728(82)80043-0
关键词: Pulse (signal processing) 、 Chemistry 、 Reaction rate constant 、 Analytical chemistry 、 Supporting electrolyte 、 Polarography 、 Electrode 、 Inorganic chemistry 、 Triton X-100 、 Seawater 、 Pulmonary surfactant
摘要: Abstract The inhibition of the electrode reaction Cd(II) in seawater as supporting electrolyte presence non-ionic surfactant T-X-100 was studied by differential pulse polarography a wide concentration range (10 −7 −5×10 −4 mol dm −3 ). kinetic parameters, rate constant k s and transfer coefficient α were estimated from shape height corresponding polarograms, using theoretical curves obtained digital simulation.
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