Molecular-sieve catalysts for the selective oxidation of linear alkanes by molecular oxygen

作者: John Meurig Thomas , Robert Raja , Gopinathan Sankar , Robert G. Bell

DOI: 10.1038/18417

关键词: RegioselectivityRedoxCatalysisPartial oxidationHydrogenOrganic chemistryAlkylSelectivityMolecular sieveChemistry

摘要: … for the oxidation of linear alkanes by molecular oxygen. The … They are thus able to use molecular oxygen as oxidant, which, in … inorganic catalyst for industrial oxidation processes. …

参考文章(26)
B. Kraushaar-Czarnetzki, W.G.M. Hoogervorst, W.H.J. Stork, Oxidation of saturated hydrocarbons involving CoAPO molecular sieves as oxidants and as catalysts Studies in Surface Science and Catalysis. ,vol. 84, pp. 1869- 1876 ,(1994) , 10.1016/S0167-2991(08)63743-X
Craig L. Hill, Activation and functionalization of alkanes Wiley. ,(1989)
Robert Raja, Paul Ratnasamy, Selective oxidation with copper complexes incorporated in molecular sieves Studies in Surface Science and Catalysis. ,vol. 101, pp. 181- 190 ,(1996) , 10.1016/S0167-2991(96)80228-X
John T. Groves, Artificial enzymes. The importance of being selective. Nature. ,vol. 389, pp. 329- 330 ,(1997) , 10.1038/38602
Gopinathan Sankar, Robert Raja, John Meurig Thomas, Redox solid catalysts for the selective oxidation of cyclohexane in air Catalysis Letters. ,vol. 55, pp. 15- 23 ,(1998) , 10.1023/A:1019093703743
Bruce R. Cook, Thomas J. Reinert, Kenneth S. Suslick, Shape selective alkane hydroxylation by metalloporphyrin catalysts Journal of the American Chemical Society. ,vol. 108, pp. 7281- 7286 ,(1986) , 10.1021/JA00283A024
L.E. Iton, I. Choi, J.A. Desjardins, V.A. Maroni, Stabilization of Co (III) in aluminophosphate molecular sieve frameworks Zeolites. ,vol. 9, pp. 535- 538 ,(1989) , 10.1016/0144-2449(89)90051-1
Philip A. Barrett, Gopinathan Sankar, Richard H. Jones, C. Richard A. Catlow, John Meurig Thomas, Interaction of acetonitrile with cobalt-containing aluminophosphates: An X-ray absorption investigation Journal of Physical Chemistry B. ,vol. 101, pp. 9555- 9562 ,(1997) , 10.1021/JP970701R
J. M. Thomas, W. J. Thomas, H. W. Salzberg, Introduction to the principles of heterogeneous catalysis ,(1967)