Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions.
作者： Hui Lv , Qi Xing , Chengtao Yue , Ziqiang Lei , Fuwei Li
DOI: 10.1039/C6CC01234E
关键词: Solvent 、 Organic chemistry 、 Carbamate 、 Photochemistry 、 Chemistry 、 Catalysis 、 Silylation 、 Carbon dioxide 、 Formylation
摘要: … polar aprotic solvent, such as DMSO or DMF, was used (entries 8 and 9). This can probably be rationalized by the good solubility of CO 2 in DMSO or DMF and the appropriate basicity/…
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