Relative Reactivities of the Isomeric Butanols and Ethanol in an Ignition Quality Tester
作者： Francis M. Haas , Amanda Ramcharan , Frederick L. Dryer
DOI: 10.1021/EF2008024
关键词: Chemistry 、 Organic chemistry 、 Physical property 、 Heptane 、 Alcohol 、 Autoignition temperature 、 Chemical engineering 、 Diesel fuel 、 Ignition system 、 Cetane number 、 Fuel oil
摘要: Ignition quality tester (IQT) derived cetane numbers (DCNs) of binary blends each individual alcohol (1-, 2-, iso-, and t-butanol ethanol) with second component (n-heptane a real distillate fuel) have been measured to explore the autoignition behavior these mixtures. This study pays particular attention effect physical property variation within among families mixtures on their apparent reactivities. The relative reactivities are dominated by chemical kinetics, while blend-specific properties affect ignitability only slightly. results firmly support DCN measurement as means characterizing mechanistic ignition chemistry behaviors fuels blends. Surprisingly, t-butanol, which has shown in other studies be least reactive pure C4 alcohol, shows suppression reactivity when blended heptane or diesel fuel for most mixture fractions. result is related lack easily abstractable H...
acs.org
sci-hub.se 参考文章(39)
Owen J. Metcalf, André Swarts, Andy Yates, A Study of the Ignition-Delay Character of n-Heptane in the IQT™ Combustion Bomb Using CFD Modelling 2007 Fuels and Emissions Conference. ,(2007) , 10.4271/2007-01-0021
Nick M. Marinov, A detailed chemical kinetic model for high temperature ethanol oxidation International Journal of Chemical Kinetics. ,vol. 31, pp. 183- 220 ,(1999) , 10.1002/(SICI)1097-4601(1999)31:3<183::AID-KIN3>3.0.CO;2-X
F.K. Mak, Economics of producing unleaded gasoline blends with Oxinol and MTBE Energy. ,vol. 11, pp. 253- 260 ,(1986) , 10.1016/0360-5442(86)90082-4
Curt R. Fischer, Daniel Klein-Marcuschamer, Gregory Stephanopoulos, Selection and optimization of microbial hosts for biofuels production. Metabolic Engineering. ,vol. 10, pp. 295- 304 ,(2008) , 10.1016/J.YMBEN.2008.06.009
Shota Atsumi, Taizo Hanai, James C. Liao, Non-fermentative pathways for synthesis of branched-chain higher alcohols as biofuels Nature. ,vol. 451, pp. 86- 89 ,(2008) , 10.1038/NATURE06450
James S. Chickos, William E. Acree, Enthalpies of Vaporization of Organic and Organometallic Compounds, 1880-2002 Journal of Physical and Chemical Reference Data. ,vol. 32, pp. 519- 878 ,(2003) , 10.1063/1.1529214
Michael R. Harper, Kevin M. Van Geem, Steven P. Pyl, Shamel S. Merchant, Guy B. Marin, William H. Green, Erratum to “Comprehensive reaction mechanism for n-butanol pyrolysis and combustion” [Combust. Flame 158 (2011) 16–41] Combustion and Flame. ,vol. 158, pp. 2075- ,(2011) , 10.1016/J.COMBUSTFLAME.2011.02.023
James A. Kenar, Gerhard Knothe, Robert O. Dunn, Thomas W. Ryan, Andrew Matheaus, Physical properties of oleochemical carbonates Journal of the American Oil Chemists' Society. ,vol. 82, pp. 201- 205 ,(2005) , 10.1007/S11746-005-5173-5
C. Togbé, G. Dayma, A. Mzé-Ahmed, P. Dagaut, Experimental and Modeling Study of the Kinetics of Oxidation of Simple Biodiesel−Biobutanol Surrogates: Methyl Octanoate−Butanol Mixtures Energy & Fuels. ,vol. 24, pp. 3906- 3916 ,(2010) , 10.1021/EF100484Q
R. Sivaramakrishnan, M.-C. Su, J. V. Michael, S. J. Klippenstein, L. B. Harding, B. Ruscic, Rate constants for the thermal decomposition of ethanol and its bimolecular reactions with OH and D: reflected shock tube and theoretical studies. Journal of Physical Chemistry A. ,vol. 114, pp. 9425- 9439 ,(2010) , 10.1021/JP104759D