Electrochemical separation study of LaF3 in molten FLiNaK salt
作者： Yafei Wang , Jianbang Ge , Weiqian Zhuo , Shaoqiang Guo , Jinsuo Zhang
DOI: 10.1016/J.JNUCMAT.2019.03.007
关键词: Metal 、 Electrode 、 Salt (chemistry) 、 Redox 、 Lanthanum 、 FLiNaK 、 Inorganic chemistry 、 Electrochemistry 、 Materials science 、 Cathodic protection
摘要: … on the tungsten and molybdenum … separation of lanthanum from FLiNaK molten salt can be realized by merely using an inert electrode. It is surprising that lanthanum can be separated …
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sci-hub.se 参考文章(11)
Frédéric Lantelme, Youssef Berghoute, Electrochemical Studies of LaCl3 and GdCl3 Dissolved in Fused LiCl‐KCl Journal of The Electrochemical Society. ,vol. 146, pp. 4137- 4144 ,(1999) , 10.1149/1.1392604
John P. Ackerman, Chemical basis for pyrochemical reprocessing of nuclear fuel Industrial & Engineering Chemistry Research. ,vol. 30, pp. 141- 145 ,(1991) , 10.1021/IE00049A022
Hao Tang, Batric Pesic, Electrochemical behavior of LaCl3 and morphology of La deposit on molybdenum substrate in molten LiCl-KCl eutectic salt Electrochimica Acta. ,vol. 119, pp. 120- 130 ,(2014) , 10.1016/J.ELECTACTA.2013.11.148
Y. Castrillejo, M.R. Bermejo, E. Barrado, A.M. Martı́nez, P. Dı́az Arocas, Solubilization of rare earth oxides in the eutectic LiCl–KCl mixture at 450 °C and in the equimolar CaCl2–NaCl melt at 550 °C Journal of Electroanalytical Chemistry. ,vol. 545, pp. 141- 157 ,(2003) , 10.1016/S0022-0728(03)00092-5
Huan Qiao, Toshiyuki Nohira, Yasuhiko Ito, Electrochemical formation of Au2Na alloy and the characteristics of (Au2Na+Au) reference electrode in a LiF–NaF–KF eutectic melt Electrochimica Acta. ,vol. 47, pp. 4543- 4549 ,(2002) , 10.1016/S0013-4686(02)00543-1
Marta Ambrová, Jana Jurišová, Vladimír Danielik, Electrochemical behaviour of lanthanum fluoride in molten fluorides Chemical Papers. ,vol. 62, pp. 559- 565 ,(2008) , 10.2478/S11696-008-0068-1
Huan Qiao, Toshiyuki Nohira, Yasuhiko Ito, Electrochemical formation of Pd–La alloy films in a LiF–NaF–KF–LaF3 melt Journal of Alloys and Compounds. ,vol. 359, pp. 230- 235 ,(2003) , 10.1016/S0925-8388(03)00203-2
S. P. Fusselman, J. J. Roy, D. L. Grimmett, L. F. Grantham, C. L. Krueger, C. R. Nabelek, T. S. Storvick, Tadashi Inoue, Takatoshi Hijikata, Kensuke Kinoshita, Yoshiharu Sakamura, Koichi Uozumi, Tsutomu Kawai, Noriaki Takahashi, Thermodynamic Properties for Rare Earths and Americium in Pyropartitioning Process Solvents Journal of The Electrochemical Society. ,vol. 146, pp. 2573- 2580 ,(1999) , 10.1149/1.1391974
David Eugene Holcomb, George F Flanagan, Gary T Mays, William David Pointer, Kevin R Robb, Graydon L Yoder Jr, Fluoride Salt-Cooled High-Temperature Reactor Technology Development and Demonstration Roadmap Oak Ridge National Laboratory. ,(2013) , 10.2172/1107839
Graydon L Yoder, Jr, Andrew T Bopp, David Eugene Holcomb, William David Pointer, Dean Wang, Advanced High Temperature Reactor Thermal Hydraulics Analysis and Salt Clean-up System Description ,(2014) , 10.2172/1163164