Origin of similarity of phase diagrams in amphiphilic and colloidal systems with competing interactions

作者: A Ciach , J Pękalski , WT Góźdź , None

DOI: 10.1039/C3SM50668A

关键词: Phase diagramAmphiphileSimilarity (geometry)Computational chemistryIsotropyChemistryChemical physicsColloidGlobular protein

摘要: We show that amphiphilic and colloidal systems with competing interactions can be described by the same Landau–Brazovskii functional. The functional is obtained a systematic coarse-graining procedure applied to isotropic interaction potentials. Microscopic expressions for coefficients in are derived. propose simple criteria distinguish effective interparticle potentials lead macro- or microsegregation. Our considerations also concern charged globular proteins aqueous solutions other short-range attraction long-range repulsion interactions.

参考文章(45)
Jean Pierre Hansen, Jean-Louis Barrat, Basic Concepts for Simple and Complex Liquids ,(2003)
Marco Tarzia, Antonio Coniglio, Pattern Formation and Glassy Phase in the ϕ 4 Theory with a Screened Electrostatic Repulsion Physical Review Letters. ,vol. 96, pp. 075702- ,(2006) , 10.1103/PHYSREVLETT.96.075702
Alina Ciach, WT Góźdź, None, 7 Nonelectrolyte solutions exhibiting structure on thenanoscale Annual Reports Section 'C' (Physical Chemistry). ,vol. 97, pp. 269- 314 ,(2001) , 10.1039/B101392K
C. Ortix, J. Lorenzana, C. Di Castro, Coulomb-frustrated phase separation phase diagram in systems with short-range negative compressibility. Physical Review Letters. ,vol. 100, pp. 246402- 246402 ,(2008) , 10.1103/PHYSREVLETT.100.246402
M. Seul, D. Andelman, Domain shapes and patterns: the phenomenology of modulated phases. Science. ,vol. 267, pp. 476- 483 ,(1995) , 10.1126/SCIENCE.267.5197.476
Christian L. Klix, C. Patrick Royall, Hajime Tanaka, Structural and dynamical features of multiple metastable glassy states in a colloidal system with competing interactions Physical Review Letters. ,vol. 104, pp. 165702- 165705 ,(2010) , 10.1103/PHYSREVLETT.104.165702
Glenn H. Fredrickson, Eugene Helfand, Fluctuation effects in the theory of microphase separation in block copolymers The Journal of Chemical Physics. ,vol. 87, pp. 697- 705 ,(1987) , 10.1063/1.453566
Francesco Sciortino, Emanuela Zaccarelli, Juan Carlos Fernandez Toledano, Colloidal systems with competing interactions: from an arrested repulsive cluster phase to a gel Soft Matter. ,vol. 5, pp. 2390- 2398 ,(2009) , 10.1039/B818169A