Intrusion of substituents into the cavity of aromatic π-electron clouds

作者: V. Boekelheide

DOI: 10.1351/PAC197544040751

关键词: Turn (biochemistry)Atomic orbitalPhotochemistryChemistryComputational chemistryChemical shiftIntrusionHydrogenAnnulene

摘要: … 765 during conformational flipping. Thus, the coalescence temperature for conformational flipping of 33 is --55 at 100 MHz, and the stable conformation of 32 in the crystalline state is …

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