Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates
作者： Takumi Hanaya , Kosuke Suzuki , Rinta Sato , Kazuya Yamaguchi , Noritaka Mizuno
DOI: 10.1039/C7DT01587A
关键词: Lacunary function 、 Bismuth 、 Polymer chemistry 、 Lone pair 、 Oxide 、 Tungsten oxide 、 Nanoclusters 、 Inorganic chemistry 、 Materials science
摘要: Three types of heterometallic bismuth–tungsten oxide nanoclusters were successfully synthesized by the reactions lacunary silicotungstates (trivacant [A-α-SiW9O34]10− and divacant [γ-SiW10O36]8−) Bi3+ in organic solvents. Lone pairs on acted as structure-directing groups these nanoclusters.
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