Metallosupramolecular Structures Derived from a Series of Diphosphine-bridged Digold(I) Metalloligands with Terminald-Penicillamine
作者： Nobuto Yoshinari , Takumi Konno
关键词: Supramolecular chemistry 、 Stereochemistry 、 Helix 、 Chemistry
摘要: In this report, we describe our recent work on the development of a new family chiral heteroleptic digold(I) metalloligands with mixed diphosphine and d-penicillaminate (d-pen), [Au2 (dppx)(d-pen-S)2 ](2-) (dppx = PPh2 (CH2 )n PPh2 , n = 1-5) their application for construction multinuclear metallosupramolecular structures. The reactions 3d metal ions produce variety heterobimetallic structures retaining metalloligand structure, ranging from discrete trinuclear to infinite helix that depend type dppx. addition, monophosphine triphosphine analogues were designed, coordination behavior is discussed show essential properties potential extensibility class metalloligands.
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