Polymer blends and interpenetrating polymer networks at the interface with solids

作者: Y Lipatov

DOI: 10.1016/S0079-6700(02)00021-7

关键词: WettingChemical engineeringAdsorptionInterpenetrating polymer networkThermodynamic stateThin layersMaterials sciencePolymerPolymer blendThin film

摘要: Abstract This review deals with a variety of the processes proceeding in polymer blends at interface solids. By contact blend solid surface, thermodynamic state changes due to physical interaction component surface. In adsorption mixtures from solutions and surface segregation one-phase there takes place formation near-surface layers compositions different composition initial blends. Such differences change conditions phase separation thin films blend. The effects under consideration depend on three parameters: A–solid, B–solid, polymers A–B. Theoretical concepts experimental data solution, are presented discussed. Special attention is paid analysis mechanisms changing presence solid. peculiarities behavior interpenetrating networks (IPNs) considered characteristic features IPNs course chemical reactions

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