Fabrication of magnetic bimetallic Fe3O4@Au–Pd hybrid nanoparticles with recyclable and efficient catalytic properties
作者： Qingdong Xia , Shanshan Fu , Guojuan Ren , Fang Chai , Jingjie Jiang
DOI: 10.1039/C6RA08602K
关键词: Bimetallic strip 、 Nanomaterial-based catalyst 、 Nanoparticle 、 Powder diffraction 、 Catalysis 、 Materials science 、 Transmission electron microscopy 、 X-ray photoelectron spectroscopy 、 Energy-dispersive X-ray spectroscopy 、 Nanotechnology
摘要: Bimetallic nanostructures show exciting potential as materials for effective catalysis. Magnetically recoverable bimetallic nanoparticles are promising catalysts chemical reactions. Here, Fe3O4@Pd and Fe3O4@Au–Pd hybrid were synthesized used catalysts. The morphology, composition, structure of the fully characterized by scanning transmission electron microscopy, energy dispersive spectroscopy, high angle annular dark-field TEM, X-ray powder diffraction, photoelectron etc. excellent catalytic activity towards reduction nitrophenols potassium hexacyanoferrate(III). In addition, magnetic heterogeneous can be easily recycled, showing good reusability; conversion higher than 99% was achieved after 6 cycles.
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sci-hub.se 参考文章(52)
Li-Li He, Pei Song, Jiu-Ju Feng, Wen-Hua Huang, Qiao-Li Wang, Ai-Jun Wang, Simple wet-chemical synthesis of alloyed PdAu nanochain networks with improved electrocatalytic properties Electrochimica Acta. ,vol. 176, pp. 86- 95 ,(2015) , 10.1016/J.ELECTACTA.2015.06.137
Chang-Hai Liu, Jie Liu, Yu-Yan Zhou, Xin-Lei Cai, Ying Lu, Xu Gao, Sui-Dong Wang, Small and uniform Pd monometallic/bimetallic nanoparticles decorated on multi-walled carbon nanotubes for efficient reduction of 4-nitrophenol Carbon. ,vol. 94, pp. 295- 300 ,(2015) , 10.1016/J.CARBON.2015.07.003
Junjie Mao, Tai Cao, Yuanjun Chen, Yuen Wu, Chen Chen, Qing Peng, Dingsheng Wang, Yadong Li, Seed-mediated synthesis of hexameric octahedral PtPdCu nanocrystals with high electrocatalytic performance Chemical Communications. ,vol. 51, pp. 15406- 15409 ,(2015) , 10.1039/C5CC06740E
Xiaojun Sun, Dong Qin, Co-titration of AgNO3 and HAuCl4: a new route to the synthesis of Ag@Ag–Au core–frame nanocubes with enhanced plasmonic and catalytic properties Journal of Materials Chemistry C. ,vol. 3, pp. 11833- 11841 ,(2015) , 10.1039/C5TC03002A
Bin Mu, Aiqin Wang, One-pot fabrication of multifunctional superparamagnetic attapulgite/Fe3O4/polyaniline nanocomposites served as an adsorbent and catalyst support Journal of Materials Chemistry. ,vol. 3, pp. 281- 289 ,(2015) , 10.1039/C4TA05367B
Wenju Xu, Huayu Yi, Yali Yuan, Pei Jing, Yaqin Chai, Ruo Yuan, George S Wilson, None, An electrochemical aptasensor for thrombin using synergetic catalysis of enzyme and porous Au@Pd core-shell nanostructures for signal amplification. Biosensors and Bioelectronics. ,vol. 64, pp. 423- 428 ,(2015) , 10.1016/J.BIOS.2014.08.091
Nikhil R. Jana, Latha Gearheart, Catherine J. Murphy, Seeding Growth for Size Control of 5−40 nm Diameter Gold Nanoparticles Langmuir. ,vol. 17, pp. 6782- 6786 ,(2001) , 10.1021/LA0104323
Christin Büchner, Leonid Lichtenstein, Stefanie Stuckenholz, Markus Heyde, Franziska Ringleb, Martin Sterrer, William E. Kaden, Livia Giordano, Gianfranco Pacchioni, Hans-Joachim Freund, Adsorption of Au and Pd on Ruthenium-Supported Bilayer Silica Journal of Physical Chemistry C. ,vol. 118, pp. 20959- 20969 ,(2014) , 10.1021/JP5055342
A. Spitale, M. A. Perez, S. Mejía-Rosales, M. J. Yacamán, M. M. Mariscal, Gold–palladium core@shell nanoalloys: experiments and simulations Physical Chemistry Chemical Physics. ,vol. 17, pp. 28060- 28067 ,(2015) , 10.1039/C4CP06012A
Meenakshisundaram Sankar, Nikolaos Dimitratos, Peter J. Miedziak, Peter P. Wells, Christopher J. Kiely, Graham J. Hutchings, Designing bimetallic catalysts for a green and sustainable future Chemical Society Reviews. ,vol. 41, pp. 8099- 8139 ,(2012) , 10.1039/C2CS35296F