Synthesis of M2Ag6S4 (M=Na, K) in supercritical ethylenediamine solvent : a novel solid containing unusual closed-shell bonding

作者: Paul T. Wood , William T. Pennington , Joseph W. Kolis

DOI: 10.1039/C39930000235

关键词: Supercritical fluidInorganic chemistryPhysical chemistrySolventEthylenediamineOctahedronChemistryOpen shell

摘要: A novel solid M2Ag6S4(M = Na, K) has been synthesized in supercritical ethylenediamine, and an unusual framework structure with extended array of face-sharing silver octahedra

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