UV-spektroskopische und photochemische untersuchungen am dibenzoplatinol-system
作者： Hans-Albert Brune , Robert Hohenadel , Günter Schmidtberg , Ulrich Ziegler
DOI: 10.1016/0022-328X(91)83062-9
关键词: Norbornadiene 、 Photochemistry 、 Chemistry 、 Metallacycle 、 Platinum 、 Bicyclic molecule 、 Reductive elimination 、 Monochromatic color 、 Irradiation 、 Biphenyl
摘要: Abstract The dibenzoplatinol system has been irradiated with monochromatic UV-radation of wavelengths λ = 253.2, 278.8, 313.7, 348.1 nm and studied respect to photochemical reactivity. All 15 compounds were completely photo-stable within the cited wavelength interval. results are discussed mechanism reductive elimination biphenyl from cis-bis(phenyl)platinum(II) complexes.
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