Photochemical formation of substituted pentacenes.

作者: Yuewei Zhao , Rajib Mondal , Douglas C. Neckers

DOI: 10.1021/JO800728P

关键词: OxygenInert gasSolid-statePhotochemistryChemistry

摘要: Substituted pentacenes (8a, 8b, 14a, and 14b) were prepared by Strating-Zwanenburg photodecarbonylation of diones (7a, 7b, 13a, 13b). The compounds are red stable in the solid state under inert atmosphere as well degassed solutions, but not air. Each is soluble common organic solvents where, unless protected, they oxygen sensitive.

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