Relative rates for hydrogen donation to benzyl radical
作者： E. Bittner , J. McGrew , B. Bockrath
DOI:
关键词: Chemistry 、 Thermal decomposition 、 Reaction rate constant 、 Molecule 、 Silylation 、 Inorganic chemistry 、 Hydrogen 、 Tetralin 、 Medicinal chemistry 、 Radical 、 Hydrogen atom abstraction
摘要: A method for determining the relative rate constants hydrogen abstraction by benzyl radicals from known or potential donor molecules is described. Rate thermal decomposition of dibenzylmercury used as a source radical were measured. Triphenylsilane deuterated at silyl position was selected reference donor. Data are presented tetralin, and expected linear relationship noted. (BLM)
osti.gov 参考文章(1)
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