Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
作者： M. A. Blesa , A. J. G. Maroto , S. I. Passaggio , N. E. Figliolia , G. Rigotti
DOI: 10.1007/BF00559350
关键词: Particle 、 Zirconium dioxide 、 Chloride 、 Dispersity 、 Hydrate 、 Cubic zirconia 、 Monoclinic crystal system 、 Mineralogy 、 Materials science 、 Crystallization 、 Chemical engineering 、 Mechanical engineering 、 General Materials Science 、 Mechanics of Materials
摘要: The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic ZrOCl 2· 8H 2 O solutions at∼ 100‡ C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure …
springer.com
sci-hub.se 参考文章(57)
R.A. Ploc, Electron diffraction from ZrO2 on αZr(101̄0) Journal of Nuclear Materials. ,vol. 115, pp. 110- 117 ,(1983) , 10.1016/0022-3115(83)90349-5
Guillermo A. Urrutia, Susana I. Passaggio, A. J. G. Maroto, Miguel A. Blesa, Model of the deposition of colloidal crud particles on the fuel elements of nuclear power plants Nuclear Science and Engineering. ,vol. 84, pp. 120- 130 ,(1983) , 10.13182/NSE83-A17718
Guillermo A. Urrutia, Alberto J. G. Maroto, Roberto Fernández-Prini, Miguel A. Blesa, General empirical model for 60Co generation in pressurized water reactors with continuous refueling Nuclear Technology. ,vol. 64, pp. 107- 114 ,(1984) , 10.13182/NT84-A33334
James A. Davis, Robert O. James, James O. Leckie, Surface ionization and complexation at the oxide/water interface Journal of Colloid and Interface Science. ,vol. 63, pp. 480- 499 ,(1978) , 10.1016/S0021-9797(78)80009-5
F.G.R Gimblett, A.A Rahman, K.S.W Sing, The origin of porosity in hydrous zirconia gels Journal of Colloid and Interface Science. ,vol. 84, pp. 337- 345 ,(1981) , 10.1016/0021-9797(81)90226-5
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
C.B. Amphlett, L.A. McDonald, M.J. Redman, SYNTHETIC INORGANIC ION-EXCHANGE MATERIALS. II. HYDROUS ZIRCONIUM OXIDE AND OTHER OXIDES Journal of Inorganic and Nuclear Chemistry. ,vol. 6, pp. 236- 245 ,(1958) , 10.1016/0022-1902(58)80153-0
R.A. Ploc, The lattice parameter of cubic ZrO2 formed on zirconium Journal of Nuclear Materials. ,vol. 99, pp. 124- 128 ,(1981) , 10.1016/0022-3115(81)90146-X
Yoshio Murase, Etsuro Kato, Thermal changes in texture of aggregates of ultra-fine crystallites in hydrolysed zirconia particles Journal of Crystal Growth. ,vol. 50, pp. 509- 514 ,(1980) , 10.1016/0022-0248(80)90100-1
Hideaki Kita, Noriaki Henmi, Katsuaki Shimazu, Hideshi Hattori, Kozo Tanabe, Measurement of acid–base properties on metal oxide surfaces in aqueous solution Journal of the Chemical Society, Faraday Transactions. ,vol. 77, pp. 2451- 2463 ,(1981) , 10.1039/F19817702451