作者: P. P. Nechaev , Yu. V. Moiseev , G. E. Zaikov , T. E. Petrova
DOI: 10.1007/BF00855650
关键词: Dimer 、 Photochemistry 、 Hydrolysis constant 、 Organic chemistry 、 Polyamide 、 Hydrolysis 、 Reactivity (chemistry) 、 Amide 、 Reaction rate constant 、 Chemistry 、 Kinetics
摘要: 1. The kinetics of the hydrolysis cyclic oligomers polycaproamide was investigated in a broad range temperatures and H2SO4 concentrations by spectrophotometric method. 2. The effective rate constant passes through maximum with increasing acid concentration. 3. A mechanism proposed. 4. The anomalous reactivity dimer is explained electrostatic interaction closely situated amide groups space.