Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls
作者： Xiaofang Li , Masayoshi Nishiura , Lihong Hu , Kyouichi Mori , Zhaomin Hou
DOI: 10.1021/JA9056213
关键词: Catalysis 、 Chemistry 、 Copolymer 、 Carbon-13 NMR 、 Isoprene 、 Ethylene 、 Cyclopentadienyl complex 、 Organic chemistry 、 Scandium 、 Medicinal chemistry 、 Cationic polymerization
摘要: The acid−base reactions between the scandium trialkyl complex Sc(CH 2 SiMe 3 ) 3 (THF) 2 and 1 equiv of Cp′−H afforded straightforwardly the corresponding mono(cyclopentadienyl…
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