Electrochemical preparation of pyronin Y thin films on gold substrates
作者： Murat Alanyalıoğlu , Mustafa Arık
DOI: 10.1002/APP.29038
关键词: Cyclic voltammetry 、 Inorganic chemistry 、 Electrolysis 、 Supporting electrolyte 、 Fluorescence spectroscopy 、 Analytical chemistry 、 Absorption (chemistry) 、 Absorption spectroscopy 、 Chronoamperometry 、 Chemistry 、 Adsorption
摘要: Cyclic voltammetry, chronoamperometry, UV-vis absorption spectroscopy, fluorescence FTIR and AFM techniques have been employed to investigate pyronin Y thin films formed on Au(111) substrates by electrochemical oxidation of monomer. The medium used in the electropolymerization was an anhydrous acetonitrile solution containing 0.1M TBAClO4 as supporting electrolyte. Anodic potential (1450 mV) has obtained from cyclic voltammetry data. Solid-state performed potential-controlled electrolysis technique. Chronoamperometry studies indicate that adsorption takes place instantaneous three-dimensional nucleation growth mechanism which is accompanied random adsorption. spectra a function electrodeposition time show insoluble Au electrode surface. FTIR-specular reflectance polymer coated reveals there possible CC coupling formation polymeric structure. A well ordered chain structure observed © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009
sci-hub.se 参考文章(27)
Mark A. Kramer, Wayne R. Tompkin, Robert W. Boyd, Nonlinear-optical interactions in fluorescein-doped boric acid glass. Physical Review A. ,vol. 34, pp. 2026- 2031 ,(1986) , 10.1103/PHYSREVA.34.2026
K. Gollnick, G. O. Schenck, Mechanism and stereoselectivity of photosensitized oxygen transfer reactions Pure and Applied Chemistry. ,vol. 9, pp. 507- 526 ,(1964) , 10.1351/PAC196409040507
A.Robert Hillman, Elizabeth F. Mallen, A spectroelectrochemical study of the electrodeposition of polythiophene films Journal of Electroanalytical Chemistry. ,vol. 243, pp. 403- 417 ,(1988) , 10.1016/0022-0728(88)80044-5
Robert W. Owens, D. Alastair Smith, STM Imaging of Cyanine Dye J-Aggregates Formed on Carboxyl-Terminated Self-Assembled Monolayers Langmuir. ,vol. 16, pp. 562- 567 ,(2000) , 10.1021/LA9905214
Duygu Ekinci, Ferhan Tümer, Ümit Demir, Synthesis and Characterization of Electropolymerized Poly(2-amino-3-cyano-4-β-naphthylthiophene) Macromolecules. ,vol. 37, pp. 7168- 7173 ,(2004) , 10.1021/MA0499019
P.O.J. Scherer, Sighart F. Fischer, On the theory of vibronic structure of linear aggregates. Application to pseudoisocyanin (PIC) Chemical Physics. ,vol. 86, pp. 269- 283 ,(1984) , 10.1016/0301-0104(84)80015-4
Anyong Zhong, Xianjun Lin, Deben Chen, Zonghua Zhou, Studies on the electrostatic self-assembly of polyelectrolytes and organic dyes with atomic force microscopy Journal of Applied Polymer Science. ,vol. 87, pp. 1029- 1033 ,(2003) , 10.1002/APP.11439
Nasr Ben Salah, Fatma Matoussi Mhalla, Mechanistic investigation of xanthene oxidation by heterogeneous and homogeneous electron transfers Journal of Electroanalytical Chemistry. ,vol. 485, pp. 42- 48 ,(2000) , 10.1016/S0022-0728(00)00091-7
T. Kato, F. Sasaki, S. Abe, S. Kobayashi, Theoretical study on the absorption spectra of pseudoisocyanine bromide (PIC-Br) molecular J-aggregates principles and practice of constraint programming. ,vol. 230, pp. 209- 221 ,(1998) , 10.1016/S0301-0104(98)00008-1
G.D. Sharma, S.K. Gupta, M.S. Roy, Electrical, optical and photovoltaic effect in pyronine G (Y) based thin film sandwich devices Thin Solid Films. ,vol. 333, pp. 176- 184 ,(1998) , 10.1016/S0040-6090(98)00841-4