Vibration-rotation bands of 15N216O14N218O

作者: C. Amiot

DOI: 10.1016/0022-2852(76)90019-9

关键词: RotationAnalytical chemistryNitrous oxideResonanceInfraredChemistryAtomic physicsPhysical and Theoretical ChemistrySpectroscopyAtomic and Molecular Physics, and Optics

摘要: Abstract The infrared spectrum of 64 bands the isotopic species 15 N 2 16 O nitrous oxide and 37 14 18 have been analyzed. studied spectral range extends from 1750 to 6000 cm −1 for 3100 O. effective rotational constants are given 44 levels comprising 21Σ, 12Π, 7Δ, 4Φ also 29 13Σ, 7Π, 6Δ, 3Φ levels. Thirty-one (20Σ, 11Π) following studied: 17 O, In a local Coriolis resonance affects 10 0 1 level. “forbidden” Δ-Σ transition 12 c 0-00 is observed in equilibrium values internuclear distances calculated.

参考文章(15)
D. K. Coles, R. H. Hughes, Microwave Spectrum of CF3Cl Physical Review. ,vol. 76, pp. 858- 858 ,(1949) , 10.1103/PHYSREV.76.858.2
C. Amiot, Vibration-rotation bands of 14N15N16O15N14N16O: 1.6–5.7 μm region Journal of Molecular Spectroscopy. ,vol. 59, pp. 191- 208 ,(1976) , 10.1016/0022-2852(76)90290-3
D. K. Coles, E. S. Elyash, J. G. Gorman, Microwave Absorption Spectra of N 2 O Physical Review. ,vol. 72, pp. 973- 973 ,(1947) , 10.1103/PHYSREV.72.973.2
Josef Plíva, Molecular constants of nitrous oxide, 14N216O Journal of Molecular Spectroscopy. ,vol. 27, pp. 461- 488 ,(1968) , 10.1016/0022-2852(68)90053-2
James K.G. Watson, The estimation of equilibrium molecular structures from zero-point rotational constants Journal of Molecular Spectroscopy. ,vol. 48, pp. 479- 502 ,(1973) , 10.1016/0022-2852(73)90112-4
Janine Connes, Hervé Delouis, Pierre Connes, Guy Guelachvili, Jean-Pierre Maillard, Guy Michel, Spectroscopie de Fourier avec transformation d'un million de points Journal of Optics. ,vol. 1, pp. 3- 22 ,(1970) , 10.1088/0029-4780/1/1/301
James M. Krell, Robert L. Sams, Vibration-rotation bands of nitrous oxide: 4.1 micron region Journal of Molecular Spectroscopy. ,vol. 51, pp. 492- 507 ,(1974) , 10.1016/0022-2852(74)90203-3
James L. Griggs, K. Narahari Rao, L.H. Jones, R.M. Potter, Vibration rotation bands of 15N218Odetermination of precise values of internuclear distances Journal of Molecular Spectroscopy. ,vol. 25, pp. 34- 61 ,(1968) , 10.1016/S0022-2852(68)80030-X