SN2P2: A Neutral Five‐Membered Sulfur–Pnictogen(III) Ring

作者: Xiaoqing Zeng , Hongmin Li , Hailong Sun , Helmut Beckers , Helge Willner

DOI: 10.1002/ANIE.201409868

关键词: Quantum chemical computationsMatrix isolationPyrolysisSulfurCrystallographyPnictogenRing (chemistry)IsotopeChemistryPhotochemistryInfrared spectroscopy

摘要: … elimination of sulfur from the unstable six-membered-ring intermediate S 2 N 2 P 2 is described. … However, the cationic binary sulfur–nitrogen 6 π electron ring S 3 N 2 2+ (1,2,4,3,5-…

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