Control of unimolecular reactions using coherent light

作者: Paul Brumer , Moshe Shapiro

DOI: 10.1016/S0009-2614(86)80171-3

关键词: Atomic physicsDiatomic moleculeSelective excitationLaserPolyatomic ionCoherence (physics)Laser beamsPhotodissociationChemistryMoleculePhysical and Theoretical ChemistryGeneral Physics and Astronomy

摘要: Abstract A method of controlling product ratios in unimolecular reactions using the coherence lasers is presented. Theory, computational results on diatomic and polyatomic molecules, an outline a proposed experiment are included.

参考文章(18)
Paul Brumer, Moshe Shapiro, Theoretical Aspects of Photodissociation and Intramolecular Dynamics Advances in Chemical Physics. ,vol. 60, pp. 371- 402 ,(2007) , 10.1002/9780470142844.CH8
Ronald D. Taylor, Paul Brumer, Dynamical instability and external perturbations: Bimolecular collisions in laser fields The Journal of Chemical Physics. ,vol. 77, pp. 854- 859 ,(1982) , 10.1063/1.443901
R. K. Sparks, K. Shobatake, L. R. Carlson, Y. T. Lee, Photofragmentation of CH3I: Vibrational distribution of the CH3 fragment Journal of Chemical Physics. ,vol. 75, pp. 3838- 3846 ,(1981) , 10.1063/1.442538
M. Shapiro, R. Bersohn, Vibrational energy distribution of the CH3 radical photodissociated from CH3I Journal of Chemical Physics. ,vol. 73, pp. 3810- 3817 ,(1980) , 10.1063/1.440611
Thomas F. George, I. Harold Zimmerman, Jian-Min Yuan, John R. Laing, Paul L. DeVries, A new concept in laser-assisted chemistry: the electronic-field representation Accounts of Chemical Research. ,vol. 10, pp. 449- 455 ,(1977) , 10.1021/AR50120A004
Moshe Shapiro, Photophysics of dissociating methyl iodide: resonance-Raman and vibronic photofragmentation maps The Journal of Physical Chemistry. ,vol. 90, pp. 3644- 3653 ,(1986) , 10.1021/J100407A035
W. R. Green, J. Lukasik, J. R. Willison, M. D. Wright, J. F. Young, S. E. Harris, Measurement of Large Cross Sections for Laser-Induced Collisions Physical Review Letters. ,vol. 42, pp. 970- 973 ,(1979) , 10.1103/PHYSREVLETT.42.970
Nicolaas Bloembergen, Eli Yablonovitch, Infrared‐laser‐induced unimolecular reactions Physics Today. ,vol. 31, pp. 23- 30 ,(1978) , 10.1063/1.2995035
K. C. Kulander, A. E. Orel, Inhibition of chemical reactions by a strong laser field Journal of Chemical Physics. ,vol. 74, pp. 6529- 6530 ,(1981) , 10.1063/1.440969