Stabilizing effects of novel phosphorus flame retardant on PET for high-temperature applications

作者: Ali Gooneie , Pietro Simonetti , Patrick Rupper , Rashid Nazir , Milijana Jovic

DOI: 10.1016/J.MATLET.2020.128225

关键词: RheologyMaterials sciencePolyethylene terephthalateStabilizer (chemistry)PhosphorusChemical engineeringFire retardantVolume concentrationLubricationExtrusion

摘要: Abstract Promising effects of DOPO-PEPA (DP), an environmental-friendly flame retardant, on the processing polyethylene terephthalate (PET) are studied via rheological experiments. DP reveals profound melt stabilization and lubrication even at low concentrations (~1 wt%). Mechanical characterization PET films confirms that direct addition powder to during extrusion has no adverse if exposed elevated temperatures for prolonged periods. This property is particularly interesting high-temperature applications, instance flexible power electronics, where mechanical flexibility should not be compromised by using a process stabilizer.

参考文章(15)
Wenfeng Shen, Xianpeng Zhang, Qijin Huang, Qingsong Xu, Weijie Song, Preparation of solid silver nanoparticles for inkjet printed flexible electronics with high conductivity Nanoscale. ,vol. 6, pp. 1622- 1628 ,(2014) , 10.1039/C3NR05479A
Linda K. Nait-Ali, Xavier Colin, Anne Bergeret, Kinetic analysis and modelling of PET macromolecular changes during its mechanical recycling by extrusion Polymer Degradation and Stability. ,vol. 96, pp. 236- 246 ,(2011) , 10.1016/J.POLYMDEGRADSTAB.2010.11.004
R Assadi, X Colin, J Verdu, Irreversible structural changes during PET recycling by extrusion Polymer. ,vol. 45, pp. 4403- 4412 ,(2004) , 10.1016/J.POLYMER.2004.04.029
John R. Campanelli, M. R. Kamal, D. G. Cooper, A kinetic study of the hydrolytic degradation of polyethylene terephthalate at high temperatures Journal of Applied Polymer Science. ,vol. 48, pp. 443- 451 ,(1993) , 10.1002/APP.1993.070480309
Gamze Güçlü, Tuncer Yalçınyuva, Saadet Özgümüş, Murat Orbay, Hydrolysis of waste polyethylene terephthalate and characterization of products by differential scanning calorimetry Thermochimica Acta. ,vol. 404, pp. 193- 205 ,(2003) , 10.1016/S0040-6031(03)00160-6
W. A. MacDonald, M. K. Looney, D. MacKerron, R. Eveson, R. Adam, K. Hashimoto, K. Rakos, Latest advances in substrates for flexible electronics Journal of The Society for Information Display. ,vol. 15, pp. 1075- 1083 ,(2007) , 10.1889/1.2825093
Michael S. Miller, Jessica C. O’Kane, Adrian Niec, R. Stephen Carmichael, Tricia Breen Carmichael, Silver nanowire/optical adhesive coatings as transparent electrodes for flexible electronics. ACS Applied Materials & Interfaces. ,vol. 5, pp. 10165- 10172 ,(2013) , 10.1021/AM402847Y
Firas Awaja, Dumitru Pavel, Recycling of PET European Polymer Journal. ,vol. 41, pp. 1453- 1477 ,(2005) , 10.1016/J.EURPOLYMJ.2005.02.005
Valerio Zardetto, Thomas M. Brown, Andrea Reale, Aldo Di Carlo, Substrates for flexible electronics: A practical investigation on the electrical, film flexibility, optical, temperature, and solvent resistance properties Journal of Polymer Science Part B: Polymer Physics. ,vol. 49, pp. 638- 648 ,(2011) , 10.1002/POLB.22227
You Seung Rim, Sang-Hoon Bae, Huajun Chen, Nicholas De Marco, Yang Yang, Recent Progress in Materials and Devices toward Printable and Flexible Sensors Advanced Materials. ,vol. 28, pp. 4415- 4440 ,(2016) , 10.1002/ADMA.201505118