A ferroelectric inorganic–organic hybrid based on NLO-phore stilbazolium
作者： Gang Xu , Yan Li , Wei-Wei Zhou , Guo-Jian Wang , Xi-Fa Long
DOI: 10.1039/B819473D
关键词: Thermal stability 、 Chemical engineering 、 Crystal structure 、 Optics 、 Phase transition 、 Nonlinear optics 、 Second-harmonic generation 、 Ferroelectricity 、 Polar 、 Hybrid material 、 Chemistry
摘要: A ferroelectric inorganic–organic hybrid based on in situ substituted stilbazolium cation (TAMS2+ = trimethylamino-N-methyl stilbazolium) has been obtained. Single-crystal X-ray structure analysis demonstrates that the NLO-phore organic component of complex is embedded into inorganic polymeric [Bi2Cl8]2− framework and shows a polar arrangement with cooperation nonsymmetric component. The measurement nonlinear optical properties show typical ferroelectricity second harmonic generation (SHG) responses as well significant improvement laser damage threshold thermal stability relative material.
rsc.org
researchgate.net 
sci-hub.se 参考文章(49)
Joseph Zyss, Molecular Nonlinear Optics: Materials, Physics, and Devices ,(2013)
Fernando Agulló-Rueda, F. Agullo-Lopez, José Manuel Cabrera, Electrooptics: Phenomena, Materials and Applications ,(1994)
A. V. Bune, V. M. Fridkin, Stephen Ducharme, L. M. Blinov, S. P. Palto, A. V. Sorokin, S. G. Yudin, A. Zlatkin, Two-dimensional ferroelectric films Nature. ,vol. 391, pp. 874- 877 ,(1998) , 10.1038/36069
R. Jakubas, U. Krzewska, G. Bator, L. Sobczyk, Structure and phase transition in (CH3NH3)3Bi2Br9. A novel improper ferroelectrics Ferroelectrics. ,vol. 77, pp. 129- 135 ,(1988) , 10.1080/00150198808223235
G. Bator, R. Jakubas, J. Zaleski, J. Mróz, Crystal structure and dielectric relaxation studies of the [N(CH3)3H]3Sb2(1−x)Bi2xCl9 mixed crystals Journal of Applied Physics. ,vol. 88, pp. 1015- 1023 ,(2000) , 10.1063/1.373771
Nataliya D. Kushch, Oleg A. Dyachenko, Victor V. Gritsenko, Patrick Cassoux, Christophe Faulmann, Akiko Kobayashi, Hayao Kobayashi, Two new cation radical bis(ethylenedithio)tetraselenafulvalene (BETS) salts, α-(BETS)6Bi3Cl12·PhCl and (BETS)2Bi2Cl8: synthesis, structure and conducting properties. First characterisation of the new trinuclear anion [Bi3Cl12]3– Journal of The Chemical Society-dalton Transactions. pp. 683- 688 ,(1998) , 10.1039/A705223E
Yong-Hua Li, Zhi-Rong Qu, Hong Zhao, Qiong Ye, Li-Xin Xing, Xi-Sen Wang, Ren-Gen Xiong, Xiao-Zeng You, A novel TGS-like inorganic-organic hybrid and a preliminary investigation of its possible ferroelectric behavior. Inorganic Chemistry. ,vol. 43, pp. 3768- 3770 ,(2004) , 10.1021/IC034672C
F. Lazarini, Structure of diethylammonium hexabromobismuthate(III) Acta Crystallographica Section C-crystal Structure Communications. ,vol. 41, pp. 1617- 1619 ,(1985) , 10.1107/S0108270185008770
J. Zaleski, A. Pietraszko, Structure at 200 and 298 K and X‐ray investigations of the phase transition at 242 K of [NH2(CH3)2]3Sb2Cl9 (DMACA) Acta Crystallographica Section B-structural Science. ,vol. 52, pp. 287- 295 ,(1996) , 10.1107/S0108768195010615
David B. Mitzi, Templating and structural engineering in organic–inorganic perovskites Journal of the Chemical Society, Dalton Transactions. pp. 1- 12 ,(2001) , 10.1039/B007070J