Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η3-1-Me-C3H4)(CN)(dppb)
作者： Alexandra Chaumonnot , Franck Lamy , Sylviane Sabo-Etienne , Bruno Donnadieu , Bruno Chaudret
DOI: 10.1021/OM049706I
关键词: Catalysis 、 Allyl cyanide 、 Cyanide 、 Chemistry 、 Isomerization 、 Adiponitrile 、 Bond cleavage 、 Photochemistry 、 Nickel 、 Medicinal chemistry
摘要: Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The mechanism supported in situ NMR monitoring and DFT studies.
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