Four-Fold Inclined Interpenetrated and Three-Fold Parallel Interpenetrated Hydrogen Bond Networks in 1,3,5-Cyclohexanetricarboxylic Acid Hydrate and Its Molecular Complex with 4,4‘-Bipyridine
作者： Balakrishna R. Bhogala , Peddy Vishweshwar , Ashwini Nangia
DOI: 10.1021/CG025537Y
关键词: Crystallization 、 Tricarboxylic acid 、 4,4'-Bipyridine 、 Crystallography 、 Hydrate 、 Bipyridine 、 Chemistry 、 Hydrogen bond 、 Crystal structure 、 Trimesic acid 、 Stereochemistry
摘要: Crystallization of 1,3,5-cyclohexanetricarboxylic acid (CTA) from EtOH affords the 1:1 hydrate, CTA.H 2 O, with 4-fold inclined interpenetrated (6,3) hydrogen-bonded networks. CTA 4,4'-bipyridine (bipy) furnishes complex, CTA.bipy.H O (2:3:1), that has 3-fold interweaving networks parallel interpenetration. The striking similarity these hydrogen bond to those found in crystal structure trimesic and its complex bipy suggests such may be engineered using retrosynthetic strategies.
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