Ionic species derived from tetrathiafulvalenes (ttfs) : cation-radicals vs cations
作者： M. Giffard , M. Sigalov , V. Khodorkovsky , A. Gorgues , G. Mabon
DOI: 10.1016/S0379-6779(98)00877-7
关键词: Chemical synthesis 、 Medicinal chemistry 、 Radical 、 Nuclear magnetic resonance spectroscopy 、 Ionic bonding 、 Ttf derivatives 、 Uv vis absorption 、 Stoichiometry 、 Protonation 、 Photochemistry 、 Chemistry
摘要: Action of acids on TTFs affords cation radicals or/and protonated species, depending conditions and substituents. The reaction TTF derivatives with has been monitored using UV-Vis nmr spectroscopy. Stoichiometric cation-radical salts have synthesized by preparative oxidation phenyliodoso diacetate an acid for comparison. A general scheme the interaction is suggested.
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