Needle concentrator for gas chromatographic determination of BTEX in aqueous samples

作者: Róbert Kubinec , Victor G Berezkin , Renáta Górová , Gabriela Addová , Helena Mračnová

DOI: 10.1016/J.JCHROMB.2003.09.009

关键词: Detection limitSorbentChemistryGas chromatographyAnalytical chemistryBTEXChromatographyEthylbenzeneAdsorptionAqueous solutionExtraction (chemistry)

摘要: Abstract A simple method of solventless extraction volatile organic compounds (BTEX) from aqueous samples was developed and validated. new arrangement the full volume inside needle capillary adsorption trap (INCAT) device with Porapak Q as a sorbent material wet alumina source desorptive water vapour flow in closed analytical system is presented. The characteristics compared purge-and-trap (PTI) for BTEX are similar; limits detection well quantification lower than 1 μg l−1.

参考文章(12)
William K. Fowler, Christina H. Duffey, Herbert C. Miller, Modification of a gas chromatographic inlet for thermal desorption of adsorbent-filled sampling tubes Analytical Chemistry. ,vol. 51, pp. 2333- 2336 ,(1979) , 10.1021/AC50050A010
P. Kuráň, R. Kubinec, I. Ostrovský, L. Soják, Purge-and-trap injection capillary gas chromatographic determination of volatile aromatic hydrocarbons in river sediment Journal of Chromatography A. ,vol. 665, pp. 133- 138 ,(1994) , 10.1016/0021-9673(94)87041-1
V.G. Berezkin, E.D. Makarov, B.V. Stolyarov, Needle-type concentrator and its application to the determination of pollutants Journal of Chromatography A. ,vol. 985, pp. 63- 65 ,(2003) , 10.1016/S0021-9673(02)01734-X
Jacek Namieśnik, Waldemar Wardencki, Solventless Sample Preparation Techniques in Environmental Analysis Journal of High Resolution Chromatography. ,vol. 23, pp. 297- 303 ,(2000) , 10.1002/(SICI)1521-4168(20000401)23:4<297::AID-JHRC297>3.0.CO;2-J
Mark E McComb, Richard D Oleschuk, Eugene Giller, Hyman D Gesser, None, Microextraction of volatile organic compounds using the inside needle capillary adsorption trap (INCAT) device Talanta. ,vol. 44, pp. 2137- 2143 ,(1997) , 10.1016/S0039-9140(97)00093-3
J. Lipinski, Automated solid phase dynamic extraction--extraction of organics using a wall coated syringe needle. Fresenius Journal of Analytical Chemistry. ,vol. 369, pp. 57- 62 ,(2001) , 10.1007/S002160000618