Methods of analysis used for the determination of selenium in milk and infant formulae: a review

作者: L.H Foster , S Sumar

DOI: 10.1016/0308-8146(95)99842-N

关键词: ReagentQuantitative analysis (chemistry)Matrix (chemical analysis)Detection limitInfant formulaAnalytical chemistryCertified reference materialsChemistrySeleniumChromatography

摘要: Abstract Selenium (Se) occurs naturally in a range of oxidation states as volatile species or analogues organic sulphur compounds. Over narrow concentration ( 3 mg/day) it possesses toxicological properties. Low levels the element most foods including milk and infant formulae require sampling procedure to be followed use certified reference material. Accurate quantitative analysis is dependent on initial digestion stage food matrix reduction Se(VI) Se(IV) final determination. In view difficulty obtaining some reagents (e.g. 2,3-diaminonapthalene), alternative procedures classical fluorometric technique need evaluated. Methods for determination Se are described detailing detection limits, sensitivity, interferences matrix-related problems.

参考文章(102)
Sareen A Stepnick Gropper, Kathryn Anderson, William M Landing, Phyllis B Acosta, None, Dietary selenium intakes and plasma selenium concentrations of formula-fed and cow's milk-fed infants. Journal of The American Dietetic Association. ,vol. 90, pp. 1547- 1550 ,(1990)
Lihua Shen, Peter Dael, Hendrik Deelstra, Evaluation of an in vitro method for the estimation of the selenium availability from cow's milk European Food Research and Technology. ,vol. 197, pp. 342- 345 ,(1993) , 10.1007/BF01242058
Antoinette Deschuytere, Kristel Vermeylen, Hendrik Deelstra, Vitamin E and selenium concentrations in milk and milkfractions European Food Research and Technology. ,vol. 184, pp. 385- 387 ,(1987) , 10.1007/BF01126662
Hubert A. M. G. Vaessen, Antonie Ooik, Collaborative test of the fluorimetric determination of selenium in a test solution, milk powder and bovine liver. European Food Research and Technology. ,vol. 185, pp. 468- 471 ,(1987) , 10.1007/BF01042810
Nestlé SA, Nestlé Nutrition workshop series Raven Press. ,(1983)
Bernhard Welz, Marianne Melcher, Jean Nève, Determination of selenium in human body fluids by hydride-generation atomic absorption spectrometry Analytica Chimica Acta. ,vol. 165, pp. 131- 140 ,(1984) , 10.1016/S0003-2670(00)85193-4
Richard E. Litov, Gerald F. Combs, Selenium in pediatric nutrition. Pediatrics. ,vol. 87, pp. 339- 351 ,(1991)
Peter Dael, Lihua Shen, Roland Renterghem, Hendrik Deelstra, Selenium content of sheep's milk and its distribution in protein fractions European Food Research and Technology. ,vol. 196, pp. 536- 539 ,(1991) , 10.1007/BF01201334