Growth mechanism and photoluminescence of CdS nanobelts on Si substrate

作者: Weifeng Liu , Chong Jia , Chuangui Jin , Lianzeng Yao , Weili Cai

DOI: 10.1016/J.JCRYSGRO.2004.05.093

关键词: PhotoluminescenceAbsorption spectroscopyCrystallographyElectron diffractionX-ray photoelectron spectroscopyTransmission electron microscopyScanning electron microscopeEvaporation (deposition)ChemistrySelected area diffraction

摘要: Abstract Large-scale CdS nanobelts were synthesized using a simple physical evaporation of particles under controlled conditions on an Si substrate without any catalyst. The are single crystals with hexagonal structure growing along the [0 0 1] direction and growth process follows vapor–solid mechanism. Two emission bands around 517 735 nm observed, X-ray photoelectron spectroscopy (XPS) results reveal that band at originates from V s + vacancies.

参考文章(20)
X. Zhang, J. Zhang, W. Wang, A Novel Route for the Preparation of Nanocomposite Magnets Advanced Materials. ,vol. 12, pp. 1441- 1444 ,(2000) , 10.1002/1521-4095(200010)12:19<1441::AID-ADMA1441>3.0.CO;2-0
J. Chrysochoos, Recombination luminescence quenching of nonstoichiometric cadmium sulfide clusters by ZnTPP The Journal of Physical Chemistry. ,vol. 96, pp. 2868- 2873 ,(1992) , 10.1021/J100186A017
Lifeng Dong, Jun Jiao, Michael Coulter, Logan Love, Catalytic growth of CdS nanobelts and nanowires on tungsten substrates Chemical Physics Letters. ,vol. 376, pp. 653- 658 ,(2003) , 10.1016/S0009-2614(03)01059-5
Peng Zhang, Lian Gao, Synthesis and characterization of CdS nanorods via hydrothermal microemulsion Langmuir. ,vol. 19, pp. 208- 210 ,(2003) , 10.1021/LA0206458
J. Butty, N. Peyghambarian, Y. H. Kao, J. D. Mackenzie, Room temperature optical gain in sol‐gel derived CdS quantum dots Applied Physics Letters. ,vol. 69, pp. 3224- 3226 ,(1996) , 10.1063/1.118017
Y. B. Li, Y. Bando, T. Sato, K. Kurashima, ZnO nanobelts grown on Si substrate Applied Physics Letters. ,vol. 81, pp. 144- 146 ,(2002) , 10.1063/1.1492008
Chintamani Nagesa Ramachandra Rao, A Govindaraj, F Leonard Deepak, NA Gunari, Manashi Nath, None, Surfactant-assisted synthesis of semiconductor nanotubes and nanowires Applied Physics Letters. ,vol. 78, pp. 1853- 1855 ,(2001) , 10.1063/1.1359145
Ying-Chun Zhu, Yoshio Bando, Dong-Feng Xue, Spontaneous growth and luminescence of zinc sulfide nanobelts Applied Physics Letters. ,vol. 82, pp. 1769- 1771 ,(2003) , 10.1063/1.1562339
Lubomir Spanhel, Markus Haase, Horst Weller, Arnim Henglein, Photochemistry of colloidal semiconductors. 20. Surface modification and stability of strong luminescing CdS particles Journal of the American Chemical Society. ,vol. 109, pp. 5649- 5655 ,(1987) , 10.1021/JA00253A015
Xiangfeng Duan, Yu Huang, Ritesh Agarwal, Charles M. Lieber, Single-nanowire electrically driven lasers Nature. ,vol. 421, pp. 241- 245 ,(2003) , 10.1038/NATURE01353