Octahedral Grignard Reagents Can Be Chiral at Magnesium

作者: Marcus Vestergren , Björn Gustafsson , Öjvind Davidsson , Mikael Håkansson

DOI: 10.1002/1521-3757(20001002)112:19<3577::AID-ANGE3577>3.0.CO;2-2

关键词: Computational chemistryOctahedronChirality (chemistry)StereoselectivityOrganic chemistryReagentMagnesiumChemistry

摘要:

参考文章(20)
Mikael Hakansson, Sharon Niezgoda, Donald J. Darensbourg, Labile Copper (I) Chloride Complexes: Preparation and Handling Inorganic Syntheses. ,vol. 32, pp. 222- 228 ,(2007) , 10.1002/9780470132630.CH37
Friedrich Bickelhaupt, Organomagnesium chemistry: Nearly hundred years but still fascinating Journal of Organometallic Chemistry. ,vol. 475, pp. 1- 14 ,(1994) , 10.1016/0022-328X(94)84002-4
T.S. Ertel, H. Bertagnolli, An EXAFS study of Grignard compounds in solution Polyhedron. ,vol. 12, pp. 2175- 2184 ,(1993) , 10.1016/S0277-5387(00)88254-6
Ulrich Knof, Alex von Zelewsky, Prädeterminierte Chiralität an Metallzentren Angewandte Chemie. ,vol. 111, pp. 312- 333 ,(1999) , 10.1002/(SICI)1521-3757(19990201)111:3<312::AID-ANGE312>3.0.CO;2-D
Mikael Håkansson, Marcus Vestergren, Björn Gustafsson, Göran Hilmersson, ISOLIERUNG UND SPONTANE ENANTIOMERENTRENNUNG VON ACHTFACH KOORDINIERTEN SAMARIUMKOMPLEXEN Angewandte Chemie. ,vol. 111, pp. 2336- 2338 ,(1999) , 10.1002/(SICI)1521-3757(19990802)111:15<2336::AID-ANGE2336>3.0.CO;2-Q
I. Abraham, W. Hörner, T.S. Ertel, H. Bertagnolli, Magnesium and bromine exafs studies of grignard compounds in solution Polyhedron. ,vol. 15, pp. 3993- 4001 ,(1996) , 10.1016/0277-5387(96)00137-4