Extraction of Am(III) at the Interface of Organic-Aqueous Two-Layer Flow in a Microchannel

作者: Yasutoshi BAN , Yoshikuni KIKUTANI , Manabu TOKESHI , Yasuji MORITA

DOI: 10.1080/18811248.2011.9711821

关键词: Phase (matter)Aqueous solutionNitric acidThermodynamic equilibriumAqueous two-phase systemAnalytical chemistryChemistryExtraction (chemistry)Cross section (physics)Microchannel

摘要: Extraction of Am(III) was performed at the interface organic-aqueous two-layer flow in a micro-channel having an asymmetric cross section. A solution 3 mol/dm3 nitric acid containing 243Am(III) and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphineoxide diluted with n-dodecane were introduced into microchannel as aqueous phase organic phase, respectively. The two phases formed stable parallel to sidewall microchannel, they separated from each other divergence point microchannel. extraction reaction proceeded phases, reached equilibrium state while passed through

参考文章(21)
A. Kawai, T. Futami, H. Kiriya, K. Katayama, K. Nishizawa, Mass-Production System of Nearly Monodisperse Diameter Gel Particles Using Droplets Formation in a Microchannel Springer Netherlands. pp. 368- 370 ,(2002) , 10.1007/978-94-010-0295-0_123
Yoshikuni Kikutani, Akihide Hibara, Hideaki Hisamoto, Manabu Tokeshi, Takehiko Kitamori, Micro integrated chemical systems for general use Lab-on-a-Chip#R##N#Miniaturized Systems for (Bio) Chemical Analysis and Synthesis. pp. 285- 307 ,(2003) , 10.1016/B978-044451100-3/50015-2
Adelina Smirnova, Kazuma Mawatari, Akihide Hibara, Mikhail A. Proskurnin, Takehiko Kitamori, Micro-multiphase laminar flows for the extraction and detection of carbaryl derivative Analytica Chimica Acta. ,vol. 558, pp. 69- 74 ,(2006) , 10.1016/J.ACA.2005.10.073
Manabu Tokeshi, Tomoko Minagawa, Kenji Uchiyama, Akihide Hibara, Kiichi Sato, Hideaki Hisamoto, Takehiko Kitamori, Continuous-flow chemical processing on a microchip by combining microunit operations and a multiphase flow network. Analytical Chemistry. ,vol. 74, pp. 1565- 1571 ,(2002) , 10.1021/AC011111Z
Akihide Hibara, Shinobu Iwayama, Shinya Matsuoka, Masaharu Ueno, Yoshikuni Kikutani, Manabu Tokeshi, Takehiko Kitamori, Surface modification method of microchannels for gas-liquid two-phase flow in microchips. Analytical Chemistry. ,vol. 77, pp. 943- 947 ,(2005) , 10.1021/AC0490088
Hiroyasu Hotokezaka, Manabu Tokeshi, Masayuki Harada, Takehiko Kitamori, Yasuhisa Ikeda, System for high-level radioactive waste using microchannel chip — extraction behavior of metal ions from aqueous phase to organic phase in microchannel Progress in Nuclear Energy. ,vol. 47, pp. 439- 447 ,(2005) , 10.1016/J.PNUCENE.2005.05.045
Hideaki Hisamoto, Takayuki Horiuchi, Kenji Uchiyama, Manabu Tokeshi, Akihide Hibara, Takehiko Kitamori, On-chip integration of sequential ion-sensing system based on intermittent reagent pumping and formation of two-layer flow. Analytical Chemistry. ,vol. 73, pp. 5551- 5556 ,(2001) , 10.1021/AC0107150
Petra S. Dittrich, Kaoru Tachikawa, Andreas Manz, Micro total analysis systems. Latest advancements and trends. Analytical Chemistry. ,vol. 78, pp. 3887- 3908 ,(2006) , 10.1021/AC0605602
Makiko Goto, Kiichi Sato, Atsushi Murakami, Manabu Tokeshi, Takehiko Kitamori, Development of a microchip-based bioassay system using cultured cells. Analytical Chemistry. ,vol. 77, pp. 2125- 2131 ,(2005) , 10.1021/AC040165G