Three-dimensional interconnected network of nanoporous CoP nanowires as an efficient hydrogen evolution cathode

作者: Shuang Gu , Hongfang Du , Abdullah M Asiri , Xuping Sun , Chang Ming Li

DOI: 10.1039/C4CP02613F

关键词: Substrate (chemistry)NanowireHydrogen evolutionNanoporousNanotechnologyCathodeMaterials science

摘要: For the first time we demonstrate topotactic synthesis of a three-dimensional (3D) interconnected network nanoporous CoP nanowires directly on Ti substrate (np-CoP NWs/Ti) via low-temperature phosphidation Co2(OH)2(CO3)2/Ti precursor and its further use as highly efficient hydrogen evolution cathode.

参考文章(44)
M. S. Dresselhaus, I. L. Thomas, Alternative energy technologies Nature. ,vol. 414, pp. 332- 337 ,(2001) , 10.1038/35104599
R LEROY, Industrial water electrolysis: Present and future International Journal of Hydrogen Energy. ,vol. 8, pp. 401- 417 ,(1983) , 10.1016/0360-3199(83)90162-3
Leanne G. Bloor, Pedro I. Molina, Mark D. Symes, Leroy Cronin, Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ Journal of the American Chemical Society. ,vol. 136, pp. 3304- 3311 ,(2014) , 10.1021/JA5003197
Michael G. Walter, Emily L. Warren, James R. McKone, Shannon W. Boettcher, Qixi Mi, Elizabeth A. Santori, Nathan S. Lewis, Solar Water Splitting Cells Chemical Reviews. ,vol. 110, pp. 6446- 6473 ,(2010) , 10.1021/CR1002326
Yang Li, M. Azad Malik, Paul O'Brien, Synthesis of Single-Crystalline CoP Nanowires by a One-Pot Metal--Organic Route Journal of the American Chemical Society. ,vol. 127, pp. 16020- 16021 ,(2005) , 10.1021/JA055963I
J. A. Turner, Sustainable Hydrogen Production Science. ,vol. 305, pp. 972- 974 ,(2004) , 10.1126/SCIENCE.1103197
T. F. Jaramillo, K. P. Jorgensen, J. Bonde, J. H. Nielsen, S. Horch, I. Chorkendorff, Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science. ,vol. 317, pp. 100- 102 ,(2007) , 10.1126/SCIENCE.1141483
Jakob Kibsgaard, Zhebo Chen, Benjamin N. Reinecke, Thomas F. Jaramillo, Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis Nature Materials. ,vol. 11, pp. 963- 969 ,(2012) , 10.1038/NMAT3439
N. S. Lewis, D. G. Nocera, Powering the planet: Chemical challenges in solar energy utilization Proceedings of the National Academy of Sciences of the United States of America. ,vol. 103, pp. 15729- 15735 ,(2006) , 10.1073/PNAS.0603395103
Mark A. Lukowski, Andrew S. Daniel, Fei Meng, Audrey Forticaux, Linsen Li, Song Jin, Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS2 Nanosheets Journal of the American Chemical Society. ,vol. 135, pp. 10274- 10277 ,(2013) , 10.1021/JA404523S